Controlling Optical Properties and Interchain Interactions in Semiconducting Polymers by Encapsulation in Periodic Nanoporous Silicas with Different Pore Sizes

2005 ◽  
Vol 109 (38) ◽  
pp. 17879-17886 ◽  
Author(s):  
Ashley J. Cadby ◽  
Sarah H. Tolbert
2011 ◽  
Vol 134 (24) ◽  
pp. 244901 ◽  
Author(s):  
Xiao-Juan Yuan ◽  
Xian-Feng Dong ◽  
Dong-Mei Li ◽  
De-Sheng Liu

2014 ◽  
Vol 17 (2) ◽  
pp. 86-92
Author(s):  
Lam Le ◽  
Tuan Anh Luu

Among semiconducting polymers, poly(3-alkylthiophene)s have attracted great attention and generated many studies over the past few years. Among them, regioregular (head-to-tail) poly(3-hexylthiophene) (P3HT) has been especially investigated due to its superior opto-electronic properties, good solubility in the most common organic solvents, chemical and thermal stabilities and also very low toxicity. These properties enable P3HT to be significantly useful in a large variety of applications such as optical sensors, smart windows, organic field effect transistors (OFETs), electrochromic devices, and solar cells. Here, we report the synthesis of poly(3-hexylthiophene) (P3HT) and investigate the optical properties of P3HT in different solvents such as chloroform, tetrahydrofuran, toluene, ethylacetate. The structures of P3HT were confirmed by nuclear magnetic resonance (1H NMR), gel permeation chromatography (GPC), Fourier transform infrared (FT-IR).


2009 ◽  
Vol 6 (7) ◽  
pp. 1620-1623 ◽  
Author(s):  
M. S. Salem ◽  
M. J. Sailor ◽  
K. Fukami ◽  
T. Sakka ◽  
Y. H. Ogata

2010 ◽  
Vol 75 ◽  
pp. 118-123
Author(s):  
Elena Dilonardo ◽  
Maria M. Giangregorio ◽  
Maria Losurdo ◽  
Pio Capezzuto ◽  
Giovanni Bruno ◽  
...  

There has been growing interest in developing new semiconducting polymers for applications in optoelectronics (OLEDs) due to their exceptional processability and appealing characteristic of manipulating electronic and optical properties by tuning of molecular structure and self-assembling. This study is an investigation on the interplay among supermolecular organization and optical properties of thin films of the poly[2-(2-ethylhexyloxy)-5-methoxy]-1, 4-phenylenedifluorovinylene (MEH-PPDFV) conjugated polymer, which has fluorinated vinylene units. This interplay is elucidated exploiting atomic force microscopy, spectroscopy ellipsometry, photoluminescence and electroluminescence. Thin films of MEH-PPDFV have been deposited by drop casting on indium-tin-oxide (ITO), quartz and glass substrates. The dependence of polymer chains self-organization and morphology on substrate surface is presented. Furthermore, it is demonstrated that the presence of F-atoms in the vinylene units of the MEH-PPDFV yields a blue optical band gap with the maximum of the fundamental HOMO-LUMO transition at 331 nm and photoluminescence at 458 nm. The OLED built with the above polymer shows a very stable blue-greenish electroluminescence that is also achieved at 504 nm.


1992 ◽  
Vol 46 (16) ◽  
pp. 10041-10047 ◽  
Author(s):  
D. Comoretto ◽  
G. Dellepiane ◽  
G. F. Musso ◽  
R. Tubino ◽  
R. Dorsinville ◽  
...  

2009 ◽  
Author(s):  
M. Baïtoul ◽  
M. Zekriti ◽  
Beverly Karplus Hartline ◽  
Renee K. Horton ◽  
Catherine M. Kaicher

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