Spectrophotometric Study of Selective Binding Behaviors of Dye Molecules by Pyridine- and Bipyridine-Modifiedβ-Cyclodextrin Derivatives with a Functional Tether in Aqueous Solution

2004 ◽  
Vol 108 (50) ◽  
pp. 19541-19549 ◽  
Author(s):  
Yu Liu ◽  
Xue-Qing Li ◽  
Yong Chen ◽  
Xu-Dong Guan
1957 ◽  
Vol 35 (12) ◽  
pp. 1454-1460 ◽  
Author(s):  
C. A. Armour ◽  
D. E. Ryan

The synthesis of a number of N-acyl substituted phenylhydroxylamines is outlined and the effect of the change in the nature of the acyl group on their usefulness as analytical reagents is described. Stability constant measurements in alcohol show an increase in stability with an increase in basicity of reagent regardless of the nature of the attached group; their ability to precipitate complexes from aqueous solution, however, is markedly dependent on the nature of the attached radical. A spectrophotometric study shows the existence of both a 1:1 and a 1:3 iron complex. A more sensitive colorimetric reagent results with an unsaturated five-membered ring as the attached grouping.


2009 ◽  
Author(s):  
Thomas Baumgärtel ◽  
Harald Graaf ◽  
Christian von Borczyskowski

2010 ◽  
Vol 63 (2) ◽  
pp. 270 ◽  
Author(s):  
Dmitry V. Bavykin ◽  
Katherine E. Redmond ◽  
Benjamin P. Nias ◽  
Alexander N. Kulak ◽  
Frank C. Walsh

The adsorption of dye molecules from aqueous solution onto the surface of titanate nanotubes (which have been synthesized via an alkaline hydrothermal treatment) has been studied. The ionic charge on the dye molecules was found to affect their ability to adsorb onto the titanate nanotube surface. In the case of (cationic) methylene blue, the adsorption was preferable on the negatively charged surface of titanate nanotubes rather than on positively charged P25 TiO2 nanoparticles. In the case of (anionic) Eriochrome Black T dye, the opposite trend was found. Herein, the dynamics of dye adsorption and the effect of pH on the adsorption capacity are considered.


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