Vibrational Mode Coupling to Ultrafast Electron Transfer in [(CN)5OsCNRu(NH3)5]-Studied by Femtosecond Infrared Spectroscopy

2003 ◽  
Vol 107 (43) ◽  
pp. 9051-9058 ◽  
Author(s):  
Alexei V. Tivanski ◽  
Chengfei Wang ◽  
Gilbert C. Walker
Keyword(s):  
Electron Transfer ◽  
Infrared Spectroscopy ◽  
Mode Coupling ◽  
Vibrational Mode ◽  
Ultrafast Electron Transfer

scholarly journals Vibrational Mode Coupling to Reverse Electron Transfer in (CN)5FeCNRu(NH3)5− in Solution

1999 ◽  
Vol 19 (1-4) ◽  
pp. 385-387
Author(s):  
Chengfei Wang ◽  
Boris Akhremitchev ◽  
Gilbert C. Walker
Keyword(s):  
Electron Transfer ◽  
Charge Transfer ◽  
Spectral Data ◽  
Infrared Spectra ◽  
High Frequency ◽  
Mode Coupling ◽  
Vibrational Mode ◽  
Time Resolved ◽  
Reverse Electron Transfer ◽  
Infrared Spectral

We present charge transfer absorption, resonance Raman and time-resolved infrared spectral data for (CN)5FeCNRu(NH3)5− in various solvents. The transient infrared spectra and anisotropies reveal both non-equilibrium vibrational populations of high frequency modes and local solvent heating.

scholarly journals The Metallocene Battery ‐ Ultrafast Electron Transfer Self Exchange Rate Accompanied by a Harmonic Height Breathing

2021 ◽  
Author(s):  
Seyyed Mohsen Beladi-Mousavi ◽  
Shamaila Sadaf ◽  
Ann-Kristin Hennecke ◽  
Jonas Klein ◽  
Arsalan Mado Mahmood ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Exchange Rate ◽  
Ultrafast Electron Transfer

Vibrationally induced rotational axis switching: A novel mechanism for vibrational mode coupling

1992 ◽  
Vol 97 (9) ◽  
pp. 5956-5963 ◽  
Author(s):  
H. Li ◽  
Gregory S. Ezra ◽  
Laura A. Philips
Keyword(s):  
Mode Coupling ◽  
Vibrational Mode ◽  
Rotational Axis ◽  
Axis Switching
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