Structural Isomerism and Competitive Proton Solvation between Methanol and Water in H+(CH3OH)m(H2O)n,m+n= 4†

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A new Zintl cluster, [(Ni@Sn9)In(Ni@Sn9)]5−, has been isolated in two distinct isomeric forms, one where both Ni@Sn9 units are coordinated to the bridging indium atom in an η3- mode, the other where one is η3- and the other η4-.


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