Phase Separation Dynamics and Reaction Kinetics of Ternary Mixture Coupled with Interfacial Chemical Reaction

2002 ◽  
Vol 106 (32) ◽  
pp. 7869-7877 ◽  
Author(s):  
Chaohui Tong ◽  
Hongdong Zhang ◽  
Yuliang Yang
2012 ◽  
Vol 8 (12) ◽  
pp. 4405-4416 ◽  
Author(s):  
Jonathan M. Page ◽  
Edna M. Prieto ◽  
Jerald E. Dumas ◽  
Katarzyna J. Zienkiewicz ◽  
Joseph C. Wenke ◽  
...  

2019 ◽  
Vol 967 ◽  
pp. 236-240
Author(s):  
Mohamed Rosnita ◽  
A.R. Razak ◽  
Mohd Mustafa Al Bakri Abdullah

An exothermic chemical reaction between cement and water or is called as hydration of cement produced heat in which gives significance impact to the cement or concrete produced. This hydration of cement is similar to geopolymerization as in geopolymerization, heat is liberated when any pozzolanic material mixes with alkaline solution. Heat released for both hydration of cement and geopolymerization can be measured in a form of calorimetric data. This paper reviews on the use of heat released information for a better understanding on the reaction kinetics of geopolymerization and correlating the heat released with several factors including concentration of alkaline solution, mixing designation and curing temperature.


2013 ◽  
Vol 28 (1) ◽  
pp. 173-182 ◽  
Author(s):  
Hui Song ◽  
Kalpit Shah ◽  
Elham Doroodchi ◽  
Terry Wall ◽  
Behdad Moghtaderi

2017 ◽  
Vol 180 ◽  
pp. 1372-1378 ◽  
Author(s):  
Balaji Mohan ◽  
Xin Cui ◽  
Kian Jon Chua

2021 ◽  
Author(s):  
Anton Makoveev ◽  
Pavel Procházka ◽  
Azin Shahsavar ◽  
Lukáš Kormoš ◽  
Tomáš Krajňák ◽  
...  

Abstract Self-assembly and on-surface synthesis are vital strategies used for fabricating surface-confined 1D or 2D supramolecular nanoarchitectures with atomic precision. In many systems, the resulting structure is determined by kinetics of processes involved, i.e., reaction rate, on-surface diffusion, nucleation, and growth, all of which are typically governed by temperature. However, other external factors have been only scarcely harnessed to control the on-surface chemical reaction kinetics and self-assembly. Here, we show that a low-energy electron beam can be used to steer chemical reaction kinetics and induce the growth of molecular phases unattainable by thermal annealing. The electron beam provides a well-controlled means of promoting the elementary reaction step, i.e., deprotonation of carboxyl groups. The reaction rate linearly increases with increasing electron beam energy beyond the threshold energy of 6 eV. Our results offer the novel prospect of controlling the self-assembly, enhancing the rate of reaction steps selectively, and thus altering the kinetic rate hierarchy.


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