Odd/Even Effect in Self-Assembly of Chiral Molecules at the Liquid−Solid Interface:  An STM Investigation of Coadsorbate Control of Self-Assembly

2002 ◽  
Vol 106 (21) ◽  
pp. 5470-5475 ◽  
Author(s):  
Dalia G. Yablon ◽  
David Wintgens ◽  
George W. Flynn
Keyword(s):  
Self Assembly ◽  
Chiral Molecules ◽  
Solid Interface

Supramolecular Chemistry at the Liquid/Solid Interface

2005 ◽  
Vol 901 ◽  
Author(s):  
Steven De Feyter ◽  
Hiroshi Uji-i ◽  
Atsushi Miura ◽  
Wael Mamdouh ◽  
Jian Zhang ◽  
...  
Keyword(s):  
Self Assembly ◽  
Scanning Tunneling ◽  
Chiral Molecules ◽  
Tunneling Microscopy ◽  
Organic Electronic Devices ◽  
Solid Interface ◽  
Spatially Resolved ◽  
Molecule Interactions ◽  
Atomically Flat ◽  
Insight Into

AbstractThe liquid/solid interface provides an ideal environment to investigate self-assembly phenomena and scanning tunneling microscopy (STM) is the preferred methodology to probe the structure and the properties of physisorbed monolayers on the nanoscale. Physisorbed monolayers are of relevance in areas such as lubrication, patterning of surfaces on the nanoscale, and thin film based organic electronic devices, to name a few. It's important to gain insight in the factors which control the ordering of molecules at the liquid/solid interface in view of the targeted properties. STM provides detailed insight into the importance of molecule-substrate (epitaxy) and molecule-molecule interactions to direct the ordering of both achiral and chiral molecules on the atomically flat surface. The electronic properties of the self-assembled physisorbed molecules can be probed by taking advantage of the operation principle of STM, revealing spatially resolved intramolecular differences within these physisorbed molecules.

Regulation of DNA Self-Assembly and DNA Hybridization by Chiral Molecules with Corresponding Biosensor Applications

2015 ◽  
Vol 87 (4) ◽  
pp. 2058-2062 ◽  
Author(s):  
Benmei Wei ◽  
Nannan Liu ◽  
Juntao Zhang ◽  
Xiaowen Ou ◽  
Ruixue Duan ◽  
...  
Keyword(s):  
Self Assembly ◽  
Dna Hybridization ◽  
Chiral Molecules ◽  
Biosensor Applications

Synthesis and 2D self-assembly at the liquid–solid interface of novel H-bonding linear π-conjugated oligomers terminated by uracil and melamine units

2014 ◽  
Vol 38 (6) ◽  
pp. 2407-2413 ◽  
Author(s):  
G. Y. Y. Chng ◽  
X. Sun ◽  
S. J. Cho ◽  
D. Rajwar ◽  
A. C. Grimsdale ◽  
...  
Keyword(s):  
Self Assembly ◽  
Conjugated Oligomers ◽  
Solid Interface

2D self-assembly of a novel π-conjugated oligomer terminated by two uracil units is solvent dependent and involves multiple intermolecular H-bonds.

Novel chiral aggregation induced emission molecules: self-assembly, circularly polarized luminescence and copper(ii) ion detection

2018 ◽  
Vol 2 (10) ◽  
pp. 1884-1892 ◽  
Author(s):  
Guangxi Huang ◽  
Rongsen Wen ◽  
Zhiming Wang ◽  
Bing Shi Li ◽  
Ben Zhong Tang
Keyword(s):  
Self Assembly ◽  
Fluorescent Chemosensor ◽  
Chiral Molecules ◽  
Ion Detection ◽  
Circularly Polarized ◽  
Aggregation Induced Emission ◽  
Circularly Polarized Luminescence ◽  
Polarized Luminescence

Two novel chiral molecules 1 and 2 were designed and synthesized. 1 displayed evident CPL activity, whereas 2 served as a highly selective and sensitive “turn-off” fluorescent chemosensor for Cu2+.

Supramolecular self-assembly of linear oligosilsesquioxanes on mica – AFM surface imaging and hydrophilicity studies

Soft Matter ◽  
2015 ◽  
Vol 11 (24) ◽  
pp. 4818-4829 ◽  
Author(s):  
Anna Kowalewska ◽  
Maria Nowacka ◽  
Adam Tracz ◽  
Tomasz Makowski
Keyword(s):  
Self Assembly ◽  
Surface Imaging ◽  
Solid Interface ◽  
Lamellar Structures ◽  
Muscovite Mica

Linear oligomeric [2-(carboxymethylthio)ethylsilsesquioxanes] (LPSQ-COOH) adsorb spontaneously on muscovite mica and form smooth, well-ordered lamellar structures at the liquid–solid interface.

Effect of Fluid Viscosity on Dynamics of Self-Assembly at Air–Water–Solid Interface

2013 ◽  
Vol 22 (3) ◽  
pp. 662-669
Author(s):  
Kwang Soon Park ◽  
Ji Hao Hoo ◽  
Rajashree Baskaran ◽  
Karl F. Bohringer
Keyword(s):  
Self Assembly ◽  
Fluid Viscosity ◽  
Solid Interface

Amphiphile self-assembly dynamics at the solution-solid interface reveal asymmetry in head/tail desorption

2018 ◽  
Vol 54 (72) ◽  
pp. 10076-10079 ◽  
Author(s):  
Henry D. Castillo ◽  
John M. Espinosa-Duran ◽  
James R. Dobscha ◽  
Daniel C. Ashley ◽  
Sibali Debnath ◽  
...  
Keyword(s):  
Self Assembly ◽  
Adsorption And Desorption ◽  
Solid Interface

Asymmetric dynamics in fundamental adsorption and desorption steps drive self-assembly at solution/solid interface.

Self-Assembly of a Flexible Porphyrin Derivative Containing Tetra Isophthalic Acids and Host–Guest Interaction at the Liquid/Solid Interface

2020 ◽  
Vol 124 (42) ◽  
pp. 23237-23242
Author(s):  
Chunyu Ma ◽  
Jianqiao Li ◽  
Siqi Zhang ◽  
Bo Liu ◽  
Wubiao Duan ◽  
...  
Keyword(s):  
Self Assembly ◽  
Porphyrin Derivative ◽  
Solid Interface

Effect of a Bromine Substituent on the Self-Assembly of an Oligopyridine at the Liquid|Solid Interface

2020 ◽  
Vol 124 (37) ◽  
pp. 20213-20221
Author(s):  
Felix D. Goll ◽  
A. Lennart Schleper ◽  
Alexander J. C. Kuehne ◽  
Ulrich Ziener
Keyword(s):  
Self Assembly ◽  
The Self ◽  
Solid Interface
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