Intracluster Electron Transfer and Reactions in Alkali Metal−Methacrylate Clusters

2001 ◽  
Vol 105 (42) ◽  
pp. 9649-9658 ◽  
Author(s):  
Hironori Tsunoyama ◽  
Keijiro Ohshimo ◽  
Fuminori Misaizu ◽  
Koichi Ohno
Keyword(s):  
Electron Transfer ◽  
Alkali Metal

Thermally Induced Electron Transfer in a CsCoFe Prussian Blue Derivative: The Specific Role of the Alkali-Metal Ion

2004 ◽  
Vol 116 (28) ◽  
pp. 3814-3817 ◽  
Author(s):  
Anne Bleuzen ◽  
Virginie Escax ◽  
Alban Ferrier ◽  
Françoise Villain ◽  
Michel Verdaguer ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Alkali Metal ◽  
Prussian Blue ◽  
Metal Ion ◽  
Specific Role ◽  
Alkali Metal Ion ◽  
Thermally Induced

Voltammetric investigation of the kinetics of alkali metal cation reduction in N,N-dimethylformamide

1975 ◽  
Vol 28 (2) ◽  
pp. 237 ◽  
Author(s):  
JW Diggle ◽  
AJ Parker ◽  
DA Owensby
Keyword(s):  
Electron Transfer ◽  
Alkali Metal ◽  
Propylene Carbonate ◽  
Rate Constant ◽  
Alkali Metal Cation ◽  
Electrode Reaction ◽  
Amalgam Electrode ◽  
Kinetics Of ◽  
Dipolar Aprotic Solvents

The standard electron-transfer heterogeneous rate constant of lithium, potassium, sodium and caesium amalgams in N,N-dimethylformamide was ascertained employing cyclic voltammetry in an effort to relate the presence of a non-equilibrium electrode reaction at the dropping lithium amalgam electrode to the variation of the lithium amalgam electrode potential with amalgam electrode con- figuration, i.e. whether streaming, dropping or stationary. Such variations are not observed at other alkali metal amalgam electrodes. ��� In the dipolar aprotic solvents the standard electron-transfer heterogeneous rate constant for the Li(Hg) electrode increases as the solvating power for Li+ decreases, i.e. dimethyl sulphoxide < di- methylformamide < propylene carbonate. Water is a much stronger solvator of Li+ than is propylene carbonate, but the electron transfer is faster in water than in propylene carbonate; the important role of entropic contributions in ion solvation is discussed as an explanation.

Dipole-moment-driven diesel soot oxidation in the presence of alkali metal chlorides

2018 ◽  
Vol 8 (4) ◽  
pp. 970-974 ◽  
Author(s):  
Hui Chen ◽  
Yexin Zhang ◽  
Jian Zhang
Keyword(s):  
Electron Transfer ◽  
Dipole Moment ◽  
Alkali Metal ◽  
Dipole Moments ◽  
Soot Oxidation ◽  
Diesel Soot ◽  
Alkali Metal Chlorides ◽  
Metal Chlorides ◽  
Diesel Soot Oxidation

The dipole moments of alkali metal chlorides drive the oxidation of soot by promoting electron transfer, justifying their excellent activities despite their poor redox abilities.

Reactions involving electron transfer. II. Reductions of enones with alkali metal solutions

1970 ◽  
Vol 92 (9) ◽  
pp. 2800-2810 ◽  
Author(s):  
Herbert O. House ◽  
Roger W. Giese ◽  
Karlheinz. Kronberger ◽  
Jean P. Kaplan ◽  
Joseph F. Simeone
Keyword(s):  
Electron Transfer ◽  
Alkali Metal
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