Reactions involving electron transfer. II. Reductions of enones with alkali metal solutions

1970 ◽  
Vol 92 (9) ◽  
pp. 2800-2810 ◽  
Author(s):  
Herbert O. House ◽  
Roger W. Giese ◽  
Karlheinz. Kronberger ◽  
Jean P. Kaplan ◽  
Joseph F. Simeone
Keyword(s):  
Electron Transfer ◽  
Alkali Metal

Thermally Induced Electron Transfer in a CsCoFe Prussian Blue Derivative: The Specific Role of the Alkali-Metal Ion

2004 ◽  
Vol 116 (28) ◽  
pp. 3814-3817 ◽  
Author(s):  
Anne Bleuzen ◽  
Virginie Escax ◽  
Alban Ferrier ◽  
Françoise Villain ◽  
Michel Verdaguer ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Alkali Metal ◽  
Prussian Blue ◽  
Metal Ion ◽  
Specific Role ◽  
Alkali Metal Ion ◽  
Thermally Induced

Intracluster Electron Transfer and Reactions in Alkali Metal−Methacrylate Clusters

2001 ◽  
Vol 105 (42) ◽  
pp. 9649-9658 ◽  
Author(s):  
Hironori Tsunoyama ◽  
Keijiro Ohshimo ◽  
Fuminori Misaizu ◽  
Koichi Ohno
Keyword(s):  
Electron Transfer ◽  
Alkali Metal

Voltammetric investigation of the kinetics of alkali metal cation reduction in N,N-dimethylformamide

1975 ◽  
Vol 28 (2) ◽  
pp. 237 ◽  
Author(s):  
JW Diggle ◽  
AJ Parker ◽  
DA Owensby
Keyword(s):  
Electron Transfer ◽  
Alkali Metal ◽  
Propylene Carbonate ◽  
Rate Constant ◽  
Alkali Metal Cation ◽  
Electrode Reaction ◽  
Amalgam Electrode ◽  
Kinetics Of ◽  
Dipolar Aprotic Solvents

The standard electron-transfer heterogeneous rate constant of lithium, potassium, sodium and caesium amalgams in N,N-dimethylformamide was ascertained employing cyclic voltammetry in an effort to relate the presence of a non-equilibrium electrode reaction at the dropping lithium amalgam electrode to the variation of the lithium amalgam electrode potential with amalgam electrode con- figuration, i.e. whether streaming, dropping or stationary. Such variations are not observed at other alkali metal amalgam electrodes. ��� In the dipolar aprotic solvents the standard electron-transfer heterogeneous rate constant for the Li(Hg) electrode increases as the solvating power for Li+ decreases, i.e. dimethyl sulphoxide < di- methylformamide < propylene carbonate. Water is a much stronger solvator of Li+ than is propylene carbonate, but the electron transfer is faster in water than in propylene carbonate; the important role of entropic contributions in ion solvation is discussed as an explanation.

Dipole-moment-driven diesel soot oxidation in the presence of alkali metal chlorides

2018 ◽  
Vol 8 (4) ◽  
pp. 970-974 ◽  
Author(s):  
Hui Chen ◽  
Yexin Zhang ◽  
Jian Zhang
Keyword(s):  
Electron Transfer ◽  
Dipole Moment ◽  
Alkali Metal ◽  
Dipole Moments ◽  
Soot Oxidation ◽  
Diesel Soot ◽  
Alkali Metal Chlorides ◽  
Metal Chlorides ◽  
Diesel Soot Oxidation

The dipole moments of alkali metal chlorides drive the oxidation of soot by promoting electron transfer, justifying their excellent activities despite their poor redox abilities.

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