Elementary Reaction Mechanism for Benzene Oxidation in Supercritical Water†

2000 ◽  
Vol 104 (45) ◽  
pp. 10576-10586 ◽  
Author(s):  
Joanna L. DiNaro ◽  
Jack B. Howard ◽  
William H. Green ◽  
Jefferson W. Tester ◽  
Joseph W. Bozzelli
Keyword(s):  
Reaction Mechanism ◽  
Supercritical Water ◽  
Elementary Reaction ◽  
Benzene Oxidation

scholarly journals Analysis of an elementary reaction mechanism for benzene oxidation in supercritical water

2000 ◽  
Vol 28 (2) ◽  
pp. 1529-1536 ◽  
Author(s):  
Joanna L. Dinaro ◽  
Jack B. Howard ◽  
William H. Green ◽  
Jefferson W. Tester ◽  
Joseph W. Bozzelli
Keyword(s):  
Reaction Mechanism ◽  
Supercritical Water ◽  
Elementary Reaction ◽  
Benzene Oxidation

Elementary reaction mechanism of diamond growth from acetylene

1994 ◽  
Vol 98 (1) ◽  
pp. 8-11 ◽  
Author(s):  
Sergei Skokov ◽  
Brian Weiner ◽  
Michael Frenklach
Keyword(s):  
Reaction Mechanism ◽  
Elementary Reaction ◽  
Diamond Growth

Polymerization and oxidation of phenols in supercritical water

2019 ◽  
Vol 80 (4) ◽  
pp. 620-633 ◽  
Author(s):  
Huiwen Zhang ◽  
Xiaoman Zhang ◽  
Lei Ding ◽  
Miao Gong ◽  
Ying Su ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Phenolic Compounds ◽  
Supercritical Water ◽  
Water Oxidation ◽  
Reaction Pathway ◽  
Radical Reaction ◽  
Dominant Factor ◽  
Supercritical Water Oxidation ◽  
Free Radical Reaction ◽  
Reaction Conditions

Abstract The treatment of toxic and difficult-to-degrade phenolic compounds has become a key issue in the coking, pharmaceutical, and chemical industries. Considering the polymerization and oxidation of phenolic compounds in supercritical water partial oxidation/supercritical water oxidation (SCWPO/SCWO), the present study reviewed the removal efficiency and reaction pathway of phenolic compounds and phenolic waste/wastewater under different reaction conditions. Temperature is the dominant factor affecting the SCWO reaction. When the oxidizing ability is insufficient, the organics polymerize to form phenolic compounds. The gradual increase of oxidant equivalent causes the intermediate product to gradually oxidize to CO2 and H2O completely. Finally, the free radical reaction mechanism is considered to be a typical SCWO reaction mechanism.

MODELING OXIDATION AND HYDROLYSIS REACTIONS IN SUPERCRITICAL WATER—FREE RADICAL ELEMENTARY REACTION NETWORKS AND THEIR APPLICATIONS

2006 ◽  
Vol 178 (1-3) ◽  
pp. 363-398 ◽  
Author(s):  
J. M. PLOEGER ◽  
P. A. BIELENBERG ◽  
J. L. DINARO-BLANCHARD ◽  
R. P. LACHANCE ◽  
J. D. TAYLOR ◽  
...  
Keyword(s):  
Free Radical ◽  
Supercritical Water ◽  
Elementary Reaction ◽  
Reaction Networks ◽  
Hydrolysis Reactions

Experimental measurements of benzene oxidation in supercritical water

AIChE Journal ◽  
2000 ◽  
Vol 46 (11) ◽  
pp. 2274-2284 ◽  
Author(s):  
Joanna L. DiNaro ◽  
Jefferson W. Tester ◽  
Jack B. Howard ◽  
Kathleen C. Swallow
Keyword(s):  
Supercritical Water ◽  
Experimental Measurements ◽  
Benzene Oxidation
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