Stereoselective Synthesis of (Z)- and (E)-Allylic Silanes by Copper-Mediated Substitution Reactions of Allylic Carbamates with Grignard Reagents

2000 ◽  
Vol 65 (6) ◽  
pp. 1601-1614 ◽  
Author(s):  
Jacqueline H. Smitrovich ◽  
K. A. Woerpel
Keyword(s):  
Stereoselective Synthesis ◽  
Grignard Reagents ◽  
Substitution Reactions ◽  
Allylic Silanes

scholarly journals Allylic Substitution Reactions with Grignard Reagents Catalyzed by Imidazolium and 4,5-Dihydroimidazolium Carbene—CuCl Complexes.

ChemInform ◽  
2006 ◽  
Vol 37 (29) ◽  
Author(s):  
Sentaro Okamoto ◽  
Satoshi Tominaga ◽  
Naoko Saino ◽  
Kouki Kase ◽  
Kentaro Shimoda
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution ◽  
Substitution Reactions

Diastereoselective Synthesis of Morpholine Derivatives from Grignard Reagents and N-Sulfinyl Imines

Synlett ◽  
2021 ◽  
Author(s):  
Eric P. A. Talbot ◽  
Joseph M. Bateman ◽  
Diana Chan ◽  
Mustafa Moroglu ◽  
Benjamin Rahemtulla
Keyword(s):  
Grignard Reagent ◽  
Stereoselective Synthesis ◽  
Grignard Reagents ◽  
Diastereoselective Synthesis ◽  
Step Process ◽  
Diastereoselective Addition ◽  
Morpholine Derivatives

The stereoselective synthesis of C3-substituted morpholine derivatives has been achieved through a two-step process involving diastereoselective addition of a Grignard reagent to a sulfinyl imine, followed by cyclization.

Sign in / Sign up

Export Citation Format

Share Document