A stereoselective synthesis of trisubstituted alkenes. Part 1. Nickel-catalysed coupling of Grignard reagents with 5-alkyl-2,3-dihydrofurans

1992 ◽  
pp. 3419-3429 ◽  
Author(s):  
Philip J. Kocieński ◽  
Martin Pritchard ◽  
Sjoerd N. Wadman ◽  
Richard J. Whitby ◽  
Clive L. Yeates
Keyword(s):  
Stereoselective Synthesis ◽  
Grignard Reagents ◽  
Trisubstituted Alkenes

A regio- and stereoselective synthesis of trisubstituted alkenes via gold(i)-catalyzed hydrophosphoryloxylation of haloalkynes

2011 ◽  
Vol 47 (27) ◽  
pp. 7851 ◽  
Author(s):  
Bathoju Chandra Chary ◽  
Sunggak Kim ◽  
Doosup Shin ◽  
Phil Ho Lee
Keyword(s):  
Stereoselective Synthesis ◽  
Trisubstituted Alkenes

Diastereoselective Synthesis of Morpholine Derivatives from Grignard Reagents and N-Sulfinyl Imines

Synlett ◽  
2021 ◽  
Author(s):  
Eric P. A. Talbot ◽  
Joseph M. Bateman ◽  
Diana Chan ◽  
Mustafa Moroglu ◽  
Benjamin Rahemtulla
Keyword(s):  
Grignard Reagent ◽  
Stereoselective Synthesis ◽  
Grignard Reagents ◽  
Diastereoselective Synthesis ◽  
Step Process ◽  
Diastereoselective Addition ◽  
Morpholine Derivatives

The stereoselective synthesis of C3-substituted morpholine derivatives has been achieved through a two-step process involving diastereoselective addition of a Grignard reagent to a sulfinyl imine, followed by cyclization.

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