Organometallic Reactions in Aqueous Media. The Nature of the Organotin Intermediate in the Tin-Mediated Allylation of Carbonyl Compounds

1999 ◽  
Vol 64 (12) ◽  
pp. 4452-4455 ◽  
Author(s):  
Tak Hang Chan ◽  
Yang ◽  
Chao Jun Li
Keyword(s):  
Carbonyl Compounds ◽  
Aqueous Media ◽  
Organometallic Reactions

Organometallic reactions in aqueous media — Antimony-mediated allylation of carbonyl compounds and the nature of allylstibine intermediates

2001 ◽  
Vol 79 (11) ◽  
pp. 1536-1540
Author(s):  
Lian-Hai Li ◽  
Tak Hang Chan
Keyword(s):  
Carbonyl Compounds ◽  
Good Yield ◽  
Allyl Bromide ◽  
Aqueous Media ◽  
Organometallic Reactions ◽  
Homoallylic Alcohols ◽  
Reaction Proceeds

Commercial antimony metal, in aqueous 1 M H(D)Cl solution, reacts with allyl bromide and aldehydes to give the corresponding homoallylic alcohols in good yield. The reaction proceeds through the formation of allylstibine intermediates. The structures of the allylstibine intermediates are likely to be allylstibine dibromide and diallylstibine bromide.Key words: allylation reaction, aqueous organometallic reactions, homoallylic alcohols, allylstibine dibromide, diallylstibine bromide.

Organometallic Reactions in Aqueous Media: The Allylations of Carbonyl Compounds Mediated in Zn/CdSO4 and Zn/SnCl2 Bimetal Systems.

ChemInform ◽  
2004 ◽  
Vol 35 (43) ◽  
Author(s):  
Cunliu Zhou ◽  
Yuqing Zhou ◽  
Jiaoyang Jiang ◽  
Zhen Xie ◽  
Zhiyong Wang ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Aqueous Media ◽  
Organometallic Reactions

Organometallic reactions in aqueous media: the allylations of carbonyl compounds mediated in Zn/CdSO 4 and Zn/SnCl 2 bimetal systems

2004 ◽  
Vol 45 (28) ◽  
pp. 5537-5540 ◽  
Author(s):  
Cunliu Zhou ◽  
Yuqing Zhou ◽  
Jiaoyang Jiang ◽  
Zhen Xie ◽  
Zhiyong Wang ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Aqueous Media ◽  
Organometallic Reactions

Organometallic Reactions in Aqueous Media. Indium-Mediated 1,3-Butadien-2-ylation of Carbonyl Compounds

2000 ◽  
Vol 2 (22) ◽  
pp. 3469-3471 ◽  
Author(s):  
Wenshuo Lu ◽  
Jihai Ma ◽  
Yang ◽  
Tak Hang Chan
Keyword(s):  
Carbonyl Compounds ◽  
Aqueous Media ◽  
Organometallic Reactions
Sign in / Sign up

Export Citation Format

Share Document