ChemInform Abstract: Organometallic Reactions in Aqueous Media. Antimony-Mediated Allylation of Carbonyl Compounds with Fluoride Salts.

ChemInform ◽  
2000 ◽  
Vol 31 (40) ◽  
pp. no-no
Author(s):  
Lian-Hai Li ◽  
Tak Hang Chan
Keyword(s):  
Carbonyl Compounds ◽  
Aqueous Media ◽  
Organometallic Reactions ◽  
Fluoride Salts

Organometallic reactions in aqueous media — Antimony-mediated allylation of carbonyl compounds and the nature of allylstibine intermediates

2001 ◽  
Vol 79 (11) ◽  
pp. 1536-1540
Author(s):  
Lian-Hai Li ◽  
Tak Hang Chan
Keyword(s):  
Carbonyl Compounds ◽  
Good Yield ◽  
Allyl Bromide ◽  
Aqueous Media ◽  
Organometallic Reactions ◽  
Homoallylic Alcohols ◽  
Reaction Proceeds

Commercial antimony metal, in aqueous 1 M H(D)Cl solution, reacts with allyl bromide and aldehydes to give the corresponding homoallylic alcohols in good yield. The reaction proceeds through the formation of allylstibine intermediates. The structures of the allylstibine intermediates are likely to be allylstibine dibromide and diallylstibine bromide.Key words: allylation reaction, aqueous organometallic reactions, homoallylic alcohols, allylstibine dibromide, diallylstibine bromide.

Organometallic Reactions in Aqueous Media: The Allylations of Carbonyl Compounds Mediated in Zn/CdSO4 and Zn/SnCl2 Bimetal Systems.

ChemInform ◽  
2004 ◽  
Vol 35 (43) ◽  
Author(s):  
Cunliu Zhou ◽  
Yuqing Zhou ◽  
Jiaoyang Jiang ◽  
Zhen Xie ◽  
Zhiyong Wang ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Aqueous Media ◽  
Organometallic Reactions

Organometallic reactions in aqueous media: the allylations of carbonyl compounds mediated in Zn/CdSO 4 and Zn/SnCl 2 bimetal systems

2004 ◽  
Vol 45 (28) ◽  
pp. 5537-5540 ◽  
Author(s):  
Cunliu Zhou ◽  
Yuqing Zhou ◽  
Jiaoyang Jiang ◽  
Zhen Xie ◽  
Zhiyong Wang ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Aqueous Media ◽  
Organometallic Reactions
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