Asymmetric Synthesis of Activated α-Amino Esters via Chromium Carbene Complex Photochemistry

1997 ◽  
Vol 62 (22) ◽  
pp. 7704-7710 ◽  
Author(s):  
Jiawang Zhu ◽  
Christopher Deur ◽  
Louis S. Hegedus
Keyword(s):  
Asymmetric Synthesis ◽  
Carbene Complex ◽  
Amino Esters ◽  
Chromium Carbene

scholarly journals Organocatalytic Asymmetric Synthesis of α-Amino Esters from Sulfoxonium Ylides

2021 ◽  
Author(s):  
Wengang Guo ◽  
Hai Huang ◽  
Jianwei Sun
Keyword(s):  
Asymmetric Synthesis ◽  
Insertion Reaction ◽  
Metal Catalyst ◽  
Insertion Reactions ◽  
Amino Esters ◽  
Carbene Insertion

Described here is the first organocatalytic asymmetric N−H insertion reaction of α-carbonyl sulfoxonium ylides. Without a metal catalyst, this reaction represents an attractive complement to the well-established carbene insertion reactions....

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