Dynamic Kinetic Asymmetric Ring-Opening/Reductive Amination Sequence of Racemic Nitroepoxides with Chiral Amines: Enantioselective Synthesis of Chiral Vicinal Diamines

2013 ◽  
Vol 78 (11) ◽  
pp. 5717-5722 ◽  
Author(s):  
Juan Agut ◽  
Andreu Vidal ◽  
Santiago Rodríguez ◽  
Florenci V. González
Keyword(s):  
Ring Opening ◽  
Reductive Amination ◽  
Enantioselective Synthesis ◽  
Chiral Amines ◽  
Vicinal Diamines ◽  
Asymmetric Ring Opening

Asymmetric ring opening of racemic epoxides for enantioselective synthesis of (S)-β-amino alcohols by a cofactor self-sufficient cascade biocatalysis system

2019 ◽  
Vol 9 (1) ◽  
pp. 70-74 ◽  
Author(s):  
Jian-Dong Zhang ◽  
Xiao-Xiao Yang ◽  
Qiao Jia ◽  
Jian-Wei Zhao ◽  
Li-Li Gao ◽  
...  
Keyword(s):  
Ring Opening ◽  
Amino Alcohols ◽  
Enantioselective Synthesis ◽  
System P ◽  
Cascade Biocatalysis ◽  
Asymmetric Ring Opening

Asymmetric ring opening of racemic epoxides to enantiopure β-amino alcohols via a cascade biocatalysis system.

Iridium/copper-cocatalyzed asymmetric ring opening reaction of azabenzonorbornadienes with amines

2015 ◽  
Vol 13 (31) ◽  
pp. 8425-8428 ◽  
Author(s):  
Chaoyuan Zeng ◽  
Fan Yang ◽  
Jingchao Chen ◽  
Jun Wang ◽  
Baomin Fan
Keyword(s):  
Ring Opening ◽  
Ring Opening Reaction ◽  
Vicinal Diamines ◽  
Asymmetric Ring Opening ◽  
Asymmetric Ring Opening Reaction

Chiral trans-vicinal diamines were synthesized via an asymmetric ring opening reaction of azabenzonorbornadienes with amines.

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