Mild and Tunable Benzoic Acid Catalysts for Rearrangement Reactions of Allylic Alcohols

J. Adam McCubbin; Samantha Voth; Oleg V. Krokhin

doi:10.1021/jo201540p

Mild and Tunable Benzoic Acid Catalysts for Rearrangement Reactions of Allylic Alcohols

The Journal of Organic Chemistry ◽

10.1021/jo201540p ◽

2011 ◽

Vol 76 (20) ◽

pp. 8537-8542 ◽

Cited By ~ 27

Author(s):

J. Adam McCubbin ◽

Samantha Voth ◽

Oleg V. Krokhin

Keyword(s):

Benzoic Acid ◽

Allylic Alcohols ◽

Acid Catalysts ◽

Rearrangement Reactions

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ChemInform Abstract: Mild and Tunable Benzoic Acid Catalysts for Rearrangement Reactions of Allylic Alcohols.

ChemInform ◽

10.1002/chin.201208036 ◽

2012 ◽

Vol 43 (8) ◽

pp. no-no

Author(s):

J. Adam McCubbin ◽

Samantha Voth ◽

Oleg V. Krokhin

Keyword(s):

Benzoic Acid ◽

Allylic Alcohols ◽

Acid Catalysts ◽

Rearrangement Reactions

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ChemInform Abstract: Synthesis of a Broad Array of Highly Functionalized, Enantiomerically Pure Cyclohexanecarboxylic Acid Derivatives by Microbial Dihydroxylation of Benzoic Acid and Subsequent Oxidative and Rearrangement Reactions.

ChemInform ◽

10.1002/chin.200202111 ◽

2010 ◽

Vol 33 (2) ◽

pp. no-no

Author(s):

Andrew G. Myers ◽

Dionicio R. Siegel ◽

Daniel J. Buzard ◽

Mark G. Charest

Keyword(s):

Benzoic Acid ◽

Enantiomerically Pure ◽

Cyclohexanecarboxylic Acid ◽

Broad Array ◽

Rearrangement Reactions

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Esterification of allylic alcohols with benzoic acid in the presence of diethyl azodicarboxylate and triphenylphosphine

Tetrahedron ◽

10.1016/0040-4020(76)85117-4 ◽

1976 ◽

Vol 32 (17) ◽

pp. 2109-2111 ◽

Cited By ~ 45

Author(s):

G. Grynkiewicz ◽

H. Burzyńska

Keyword(s):

Benzoic Acid ◽

Allylic Alcohols ◽

Diethyl Azodicarboxylate

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ChemInform Abstract: ESTERIFICATION OF ALLYLIC ALCOHOLS WITH BENZOIC ACID IN THE PRESENCE OF DIETHYL AZODICARBOXYLATE AND TRIPHENYLPHOSPHINE

Chemischer Informationsdienst ◽

10.1002/chin.197652152 ◽

1976 ◽

Vol 7 (52) ◽

pp. no-no

Author(s):

G. GRYNKIEWICZ ◽

H. BURZYNSKA

Keyword(s):

Benzoic Acid ◽

Allylic Alcohols ◽

Diethyl Azodicarboxylate

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Esterification of benzoic acid using Ti3AlC2 and SO42−/Ti3AlC2 ceramic as acid catalysts

Ceramics International ◽

10.1016/j.ceramint.2013.04.077 ◽

2013 ◽

Vol 39 (8) ◽

pp. 9731-9736 ◽

Cited By ~ 13

Author(s):

Mingzhu Wu ◽

Junming Guo ◽

Ying Li ◽

Yingjie Zhang

Keyword(s):

Benzoic Acid ◽

Acid Catalysts

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Synthesis of a Broad Array of Highly Functionalized, Enantiomerically Pure Cyclohexanecarboxylic Acid Derivatives by Microbial Dihydroxylation of Benzoic Acid and Subsequent Oxidative and Rearrangement Reactions

Organic Letters ◽

10.1021/ol010151m ◽

2001 ◽

Vol 3 (18) ◽

pp. 2923-2926 ◽

Cited By ~ 64

Author(s):

Andrew G. Myers ◽

Dionicio R. Siegel ◽

Daniel J. Buzard ◽

Mark G. Charest

Keyword(s):

Benzoic Acid ◽

Enantiomerically Pure ◽

Cyclohexanecarboxylic Acid ◽

Broad Array ◽

Rearrangement Reactions

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TEM characterization of proton-exchanged LiNbO3 optical waveguides

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010014395x ◽

1986 ◽

Vol 44 ◽

pp. 480-481

Author(s):

W. E. Lee

Keyword(s):

Refractive Index ◽

Benzoic Acid ◽

Optical Waveguides ◽

Total Internal Reflection ◽

Index Of Refraction ◽

Optical Measurements ◽

Lithium Ions ◽

Wide Channel ◽

Tem Characterization

An optical waveguide consists of a several-micron wide channel with a slightly different index of refraction than the host substrate; light can be trapped in the channel by total internal reflection.Optical waveguides can be formed from single-crystal LiNbO3 using the proton exhange technique. In this technique, polished specimens are masked with polycrystal1ine chromium in such a way as to leave 3-13 μm wide channels. These are held in benzoic acid at 249°C for 5 minutes allowing protons to exchange for lithium ions within the channels causing an increase in the refractive index of the channel and creating the waveguide. Unfortunately, optical measurements often reveal a loss in waveguiding ability up to several weeks after exchange.

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