Nanosized Rigid π-Conjugated Molecular Heterojunctions with Multi[60]fullerenes:  Facile Synthesis and Photophysical Properties

2006 ◽  
Vol 71 (12) ◽  
pp. 4400-4410 ◽  
Author(s):  
Jin-Liang Wang ◽  
Xiao-Fei Duan ◽  
Bi Jiang ◽  
Liang-Bing Gan ◽  
Jian Pei ◽  
...  
2020 ◽  
Vol 16 ◽  
pp. 1683-1692 ◽  
Author(s):  
Dominik Göbel ◽  
Marius Friedrich ◽  
Enno Lork ◽  
Boris J Nachtsheim

Herein, we present a facile synthesis of three azide-functionalized fluorophores and their covalent attachment as triazoles in Huisgen-type cycloadditions with model alkynes. Besides two ortho- and para-bromo-substituted benzaldehydes, the azide functionalization of a fluorene-based structure will be presented. The copper(I)-catalyzed azide–alkyne cycloaddition (CuAAC) of the so-synthesized azide-functionalized bromocarbaldehydes with terminal alkynes, exhibiting different degrees of steric demand, was performed in high efficiency. Finally, we investigated the photophysical properties of the azide-functionalized arenes and their covalently linked triazole derivatives to gain deeper insight towards the effect of these covalent linkers on the emission behavior.


2019 ◽  
Vol 6 (11) ◽  
pp. 1885-1890 ◽  
Author(s):  
Shengsheng Cui ◽  
Guilin Zhuang ◽  
Jinyi Wang ◽  
Qiang Huang ◽  
Shengda Wang ◽  
...  

A novel multifunctionalized carbon nanoring was facilely synthesized, which demonstrates an unusual hypsochromic shift in the emission spectrum with interesting photophysical properties.


2020 ◽  
Vol 85 (5) ◽  
pp. 3879-3886
Author(s):  
Wenqiang Ye ◽  
Xiaobin Li ◽  
Bingbing Ding ◽  
Chenchen Wang ◽  
Mohini Shrestha ◽  
...  

2016 ◽  
Vol 2016 ◽  
pp. 1-9
Author(s):  
Kyong-Hoon Choi ◽  
Jung-Gil Kim ◽  
Byungman Kang ◽  
Ho-Joong Kim ◽  
Bong Joo Park

We developed a two-step chemical bonding process using photosensitizer molecules to fabricate photofunctional nanolayer coatings on hematoporphyrin- (HP-) coated Ti substrates. In the first step, 3-aminopropyltriethoxysilane was covalently functionalized onto the surface of the Ti substrates to provide heterogeneous sites for immobilizing the HP molecules. Then, HP molecules with carboxyl groups were chemically attached to the amine-terminated nanolayer coatings via a carbodiimide coupling reaction. The microstructure and elemental and phase composition of the HP-coated Ti substrates were investigated using field-emission scanning electron microscopy and energy-dispersive X-ray spectrometry. The photophysical properties of the photofunctional nanolayer coatings were confirmed using reflectance ultraviolet-visible absorption and emission spectrophotometry. The singlet oxygen generation efficiency of the photofunctional nanolayer coatings was determined using the decomposition reaction of 1,3-diphenylisobenzofuran. The HP-coated Ti substrates exhibited good biocompatibility without any cytotoxicity, and these nanolayer coatings generated singlet oxygen, which can kill microorganisms using only visible light.


Tetrahedron ◽  
2016 ◽  
Vol 72 (49) ◽  
pp. 8066-8072 ◽  
Author(s):  
Tingting Yang ◽  
Huixia Xu ◽  
Bo Zhao ◽  
Peng Tao ◽  
Peng Sun ◽  
...  

ChemInform ◽  
2005 ◽  
Vol 36 (51) ◽  
Author(s):  
Takanobu Sanji ◽  
Hiroyuki Ishiwata ◽  
Tomoyoshi Kaizuka ◽  
Masato Tanaka ◽  
Hideki Sakurai ◽  
...  

2016 ◽  
Vol 4 (36) ◽  
pp. 8422-8428 ◽  
Author(s):  
Jinfeng Zhou ◽  
Lizhi Gai ◽  
John Mack ◽  
Zhikuan Zhou ◽  
Hailin Qiu ◽  
...  

The facile synthesis of novel orthogonally arranged Rh(iii) porphyrin–aza-BODIPY conjugates is described. The conjugates combine the advantages of the near-IR (NIR) absorption of aza-BODPY dye with the high triplet state of rhodium porphyrins.


2008 ◽  
Vol 73 (5) ◽  
pp. 1809-1817 ◽  
Author(s):  
Tinghua Xu ◽  
Ran Lu ◽  
Xingliang Liu ◽  
Peng Chen ◽  
Xianping Qiu ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document