Regioselective Oxygenative Tetraamination of [60]Fullerene. Fullerene-mediated Reduction of Molecular Oxygen by Amine via Ground State Single Electron Transfer in Dimethyl Sulfoxide

2005 ◽  
Vol 70 (12) ◽  
pp. 4826-4832 ◽  
Author(s):  
Hiroyuki Isobe ◽  
Takatsugu Tanaka ◽  
Waka Nakanishi ◽  
Loïc Lemiègre ◽  
Eiichi Nakamura
Keyword(s):  
Electron Transfer ◽  
Dimethyl Sulfoxide ◽  
Molecular Oxygen ◽  
Ground State ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Mediated Reduction

scholarly journals Moderate oxidation levels of Ru nanoparticles enhance molecular oxygen activation for cross-dehydrogenative-coupling reactions via single electron transfer

RSC Advances ◽  
2017 ◽  
Vol 7 (53) ◽  
pp. 33078-33085 ◽  
Author(s):  
Mu Lin ◽  
Lin-Xiu Dai ◽  
Jun Gu ◽  
Li-Qun Kang ◽  
Yu-Hao Wang ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Molecular Oxygen ◽  
Surface Oxidation ◽  
Oxygen Activation ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Coupling Reactions ◽  
Ru Nanoparticles ◽  
Dehydrogenative Coupling ◽  
Altered Surface

Ruthenium nanoparticles with altered surface oxidation states showed a volcano shaped relationship in molecular oxygen activation via single electron transfer for cross-dehydrogenative-coupling reactions.

Reversal of Polarity by Catalytic SET Oxidation: Synthesis of Azabicyclo[m.n.o]alkanes via Chemoselective Reduction of Amidines

2021 ◽  
Author(s):  
Sundarababu Baskaran ◽  
Kirana D V ◽  
Kanak Kanti Das
Keyword(s):  
Electron Transfer ◽  
Stereoselective Synthesis ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Catalytic Method ◽  
One Pot ◽  
Oxidative System ◽  
Oxidation Synthesis

A one-pot catalytic method has been developed for the stereoselective synthesis of cyclopropane-fused cyclic amidines using CuBr2/K2S2O8 as an efficient single electron transfer (SET) oxidative system. The generality of this...

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