Perchloric Acid Catalyzed Aromatic Mercuration in Acetic Acid Solution. III. Relative Reactivity of Aromatic Substrates

1967 ◽  
Vol 32 (3) ◽  
pp. 756-759 ◽  
Author(s):  
A Kresge ◽  
Herbert Brown
1948 ◽  
Vol 26b (1) ◽  
pp. 104-113 ◽  
Author(s):  
G. E. Dunn ◽  
J. C. MacKenzie ◽  
George F Wright

Titration of a series of secondary amines with sulphuric or perchloric acid in acetic acid shows that those amines which do not require a chloride catalyst for their nitrations are more weakly proton-accepting than the amines which cannot be nitrated without catalyst. The weak proton-acceptance of imino-bis-acetonitrile which can be nitrated without catalyst is further typified by its tendency to co-ordinate with itself in 16% association in acetic acid solution. By contrast, dibutylamine, which cannot be nitrated without catalyst, is not associated in this medium.


2016 ◽  
Vol 10 (2) ◽  
pp. 135-139 ◽  
Author(s):  
Valentina Chernova ◽  
◽  
Angela Shurshina ◽  
Elena Kulish ◽  
Gennady Zaikov ◽  
...  

Some ways of estimating the values of the intrinsic viscosity of chitosan were analyzed. It was shown that the method of Irzhak and Baranov for estimating the current value of the intrinsic viscosity allows to adequately estimates the conformational state of the macromolecular coil and its degree of swelling.


2010 ◽  
Vol 82 (2) ◽  
pp. 251-255 ◽  
Author(s):  
H.M.P. Naveen Kumar ◽  
M.N. Prabhakar ◽  
C. Venkata Prasad ◽  
K. Madhusudhan Rao ◽  
T.V. Ashok Kumar Reddy ◽  
...  

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