Study on the initiation mechanism upon oxidation of methylaromatic hydrocarbons in presence of cobalt acetate and sodium bromide in acetic acid solution

1975 ◽  
Vol 40 (7) ◽  
pp. 2084-2092 ◽  
Author(s):  
S. Ivanov ◽  
M. Hinkova
1965 ◽  
Vol 43 (5) ◽  
pp. 1306-1317 ◽  
Author(s):  
Allan S. Hay ◽  
Harry S. Blanchard

Cobalt acetate bromide in acetic acid solution is an extraordinarily active catalyst for the autoxidation of hydrocarbons. Carboxylic acids and ketones are readily prepared in high yields at moderate temperatures and at atmospheric pressure. In addition, benzylic and allylic groups can be converted to esters of the corresponding alcohols, and the oxidation of tetralin can be controlled to give either α-tetralone or 1,2-dihydronaphthalene as the major product. A mechanism for these reactions is postulated.


2016 ◽  
Vol 10 (2) ◽  
pp. 135-139 ◽  
Author(s):  
Valentina Chernova ◽  
◽  
Angela Shurshina ◽  
Elena Kulish ◽  
Gennady Zaikov ◽  
...  

Some ways of estimating the values of the intrinsic viscosity of chitosan were analyzed. It was shown that the method of Irzhak and Baranov for estimating the current value of the intrinsic viscosity allows to adequately estimates the conformational state of the macromolecular coil and its degree of swelling.


2010 ◽  
Vol 82 (2) ◽  
pp. 251-255 ◽  
Author(s):  
H.M.P. Naveen Kumar ◽  
M.N. Prabhakar ◽  
C. Venkata Prasad ◽  
K. Madhusudhan Rao ◽  
T.V. Ashok Kumar Reddy ◽  
...  

1944 ◽  
Vol 66 (10) ◽  
pp. 1752-1755 ◽  
Author(s):  
Herbert S. Anker ◽  
Konrad Bloch

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