Concise Syntheses of Nonracemic γ-Fluoroalkylated Allylic Alcohols and Amines Via an Enantiospecific Palladium-Catalyzed Allylic Substitution Reaction

2002 ◽  
Vol 67 (6) ◽  
pp. 1768-1775 ◽  
Author(s):  
Tsutomu Konno ◽  
Kensuke Nagata ◽  
Takashi Ishihara ◽  
Hiroki Yamanaka
Keyword(s):  
Substitution Reaction ◽  
Allylic Alcohols ◽  
Allylic Substitution ◽  
Palladium Catalyzed

Palladium-Catalyzed Allylic Substitution Reaction of Benzothiazolylacetamide with Allylic Alcohols in Water

2019 ◽  
Vol 84 (16) ◽  
pp. 10111-10119 ◽  
Author(s):  
Shulei Pan ◽  
Binqiang Wu ◽  
Jinjin Hu ◽  
Ruigang Xu ◽  
Min Jiang ◽  
...  
Keyword(s):  
Substitution Reaction ◽  
Allylic Alcohols ◽  
Allylic Substitution ◽  
Palladium Catalyzed

Palladium Catalyzed Controllable Mono‐ or Di‐Allylic Substitution Reaction of Benzothiazolylacetate with Allylic Alcohols

2019 ◽  
Vol 361 (6) ◽  
pp. 1322-1334 ◽  
Author(s):  
Peipei Yan ◽  
Shulei Pan ◽  
Jinjin Hu ◽  
Limei Lu ◽  
Xiaofei Zeng ◽  
...  
Keyword(s):  
Substitution Reaction ◽  
Allylic Alcohols ◽  
Allylic Substitution ◽  
Palladium Catalyzed

Direct enantioselective allylic substitution of 4-hydroxycoumarin derivatives with branched allylic alcohols via iridium catalysis

2020 ◽  
Vol 56 (60) ◽  
pp. 8404-8407
Author(s):  
Ruigang Xu ◽  
Kai Li ◽  
Jiaqi Wang ◽  
Jiamin Lu ◽  
Lina Pan ◽  
...  
Keyword(s):  
Substitution Reaction ◽  
Allylic Alcohols ◽  
Allylic Substitution ◽  
Iridium Catalysis ◽  
High Yields

An iridium catalysed direct asymmetric allylic substitution reaction of 4-hydroxycoumarin derivatives with allylic alcohols with remarkably high yields and excellent enantioselectivities was realized.

scholarly journals Breaking conjugation: unusual regioselectivity with 2-substituted allylic substrates in the Tsuji–Trost reaction

2014 ◽  
Vol 5 (3) ◽  
pp. 1241-1250 ◽  
Author(s):  
Byeong-Seon Kim ◽  
Mahmud M. Hussain ◽  
Per-Ola Norrby ◽  
Patrick J. Walsh
Keyword(s):  
Substitution Reaction ◽  
Allylic Substitution ◽  
Palladium Catalyzed

We describe the unusual regioselectivity of the palladium-catalyzed Tsuji–Trost allylic substitution reaction with 1,2,3-trisubstituted allylic substrates.

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