Alkaline Hydrolysis of Ethyl Benzoate in Aqueous Dimethyl Sulfoxide

1964 ◽  
Vol 29 (7) ◽  
pp. 2039-2040 ◽  
Author(s):  
Donald D. Roberts
Keyword(s):  
Dimethyl Sulfoxide ◽  
Alkaline Hydrolysis ◽  
Ethyl Benzoate ◽  
Hydrolysis Of

Solvent Effect of Dimethyl Sulfoxide on Alkaline Hydrolysis of Amide

1974 ◽  
Vol 22 (4) ◽  
pp. 864-870 ◽  
Author(s):  
ITARU KOJO ◽  
SHOJI AWAZU ◽  
MANABU HANANO
Keyword(s):  
Solvent Effect ◽  
Dimethyl Sulfoxide ◽  
Alkaline Hydrolysis ◽  
Hydrolysis Of

Alkaline hydrolysis of dicarboxylic esters in aqueous dimethyl sulfoxide

1967 ◽  
Vol 8 (52) ◽  
pp. 5275-5280 ◽  
Author(s):  
N. Venkatasubramanian ◽  
G.Venkoba Rao
Keyword(s):  
Dimethyl Sulfoxide ◽  
Alkaline Hydrolysis ◽  
Hydrolysis Of

THE EFFECT ON REACTION RATES CAUSED BY THE SUBSTITUTION OF C14 FOR C12: I. THE ALKALINE HYDROLYSIS OF CARBOXYL-LABELED ETHYL BENZOATE

1949 ◽  
Vol 27b (10) ◽  
pp. 807-812 ◽  
Author(s):  
William H. Stevens ◽  
Richard W. Attree
Keyword(s):  
Alkaline Hydrolysis ◽  
Rate Constants ◽  
Room Temperature ◽  
Reaction Rates ◽  
Ethyl Benzoate ◽  
Hydrolysis Rate ◽  
Rate Of Hydrolysis ◽  
Hydrolysis Of

A study of the alkaline hydrolysis of C14 carboxyl-labeled ethyl benzoate has shown that the substitution of C14 for C12 changes the rate of hydrolysis of the ester. Ester molecules containing C14 hydrolyze at a slower rate than normal ester molecules. The ratio of the hydrolysis rate constants at room temperature has been found to be 0.86 ± 0.016.

Influence of medium on alkaline hydrolysis of succinic acid monomethyl and monopropyl esters

1980 ◽  
Vol 45 (11) ◽  
pp. 2873-2882
Author(s):  
Vladislav Holba ◽  
Ján Benko
Keyword(s):  
Succinic Acid ◽  
Kinetic Parameters ◽  
Alkaline Hydrolysis ◽  
Specific Interactions ◽  
Nonaqueous Media ◽  
The Media ◽  
Kinetics Of ◽  
Hydrolysis Of

The kinetics of alkaline hydrolysis of succinic acid monomethyl and monopropyl esters were studied in mixed aqueous-nonaqueous media at various temperatures and ionic strengths. The results of measurements are discussed in terms of electrostatic and specific interactions between the reactants and other components of the reaction mixture. The kinetic parameters in the media under study are related to the influence of the cosolvent on the solvation sphere of the reactants.

Sign in / Sign up

Export Citation Format

Share Document