Lanthanides in organic synthesis. 4. Reduction of .alpha.,.beta.-epoxy ketones with samarium diiodide. A route to chiral, nonracemic aldols

Gary A. Molander; Gregory Hahn

doi:10.1021/jo00363a038

Lanthanides in organic synthesis. 4. Reduction of .alpha.,.beta.-epoxy ketones with samarium diiodide. A route to chiral, nonracemic aldols

The Journal of Organic Chemistry ◽

10.1021/jo00363a038 ◽

1986 ◽

Vol 51 (13) ◽

pp. 2596-2599 ◽

Cited By ~ 136

Author(s):

Gary A. Molander ◽

Gregory Hahn

Keyword(s):

Organic Synthesis ◽

Samarium Diiodide ◽

Alpha Beta ◽

Epoxy Ketones

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ChemInform Abstract: Lanthanides in Organic Synthesis. Part 4. Reduction of αβ-Epoxy Ketones with Samarium Diiodide. A Route to Chiral, Nonracemic Aldols.

ChemInform ◽

10.1002/chin.198703110 ◽

1987 ◽

Vol 18 (3) ◽

Author(s):

G. A. MOLANDER ◽

G. HAHN

Keyword(s):

Organic Synthesis ◽

Samarium Diiodide ◽

Epoxy Ketones

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.alpha.,.beta.-Epoxy sulfoxides as useful intermediates in organic synthesis. 22. Stereospecific desulfinylation of sulfinylaziridines with alkylmetals: a novel synthesis including asymmetric synthesis of (Z)-N-arylaziridines and some mechanistic studies

The Journal of Organic Chemistry ◽

10.1021/jo00277a041 ◽

1989 ◽

Vol 54 (16) ◽

pp. 3973-3978 ◽

Cited By ~ 71

Author(s):

Tsuyoshi Satoh ◽

Takahiko Sato ◽

Teruhiko Oohara ◽

Koji Yamakawa

Keyword(s):

Asymmetric Synthesis ◽

Organic Synthesis ◽

Mechanistic Studies ◽

Novel Synthesis ◽

Alpha Beta

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Silyl Nitronates in Organic Synthesis. Silylation of Secondary Nitro Compounds. Preparation of Nitroso Compounds and alpha,beta-Unsaturated Aldehydes.

Acta Chemica Scandinavica ◽

10.3891/acta.chem.scand.35b-0643 ◽

1981 ◽

Vol 35b ◽

pp. 643-648 ◽

Cited By ~ 18

Author(s):

Somir K. Mukerji ◽

Kurt B. G. Torssell ◽

Christina Ullenius ◽

Povl Krogsgaard-Larsen ◽

Ulrika Örn

Keyword(s):

Organic Synthesis ◽

Nitro Compounds ◽

Nitroso Compounds ◽

Unsaturated Aldehydes ◽

Silyl Nitronates ◽

Alpha Beta

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ChemInform Abstract: Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction

ChemInform ◽

10.1002/chin.201347232 ◽

2013 ◽

Vol 44 (47) ◽

pp. no-no

Author(s):

Dhandapani V. Sadasivam ◽

Kimberly A. Choquette ◽

Robert A. Flowers

Keyword(s):

Organic Synthesis ◽

Samarium Diiodide ◽

Barbier Reaction

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ChemInform Abstract: Lanthanoids in Organic Synthesis. Part 6. Stereocontrolled Cyclization Reactions Mediated by Samarium Diiodide.

ChemInform ◽

10.1002/chin.198722098 ◽

1987 ◽

Vol 18 (22) ◽

Author(s):

G. A. MOLANDER ◽

J. B. ETTER ◽

P. W. ZINKE

Keyword(s):

Organic Synthesis ◽

Samarium Diiodide ◽

Cyclization Reactions

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Lanthanides in organic synthesis. 5. Reduction of vinyloxiranes with samarium diiodide. An efficient route to functionalized chiral, non-racemic (E)-allylic alcohols

The Journal of Organic Chemistry ◽

10.1021/jo00376a039 ◽

1986 ◽

Vol 51 (26) ◽

pp. 5259-5264 ◽

Cited By ~ 54

Author(s):

Gary A. Molander ◽

Bruce E. La Belle ◽

Gregory Hahn

Keyword(s):

Organic Synthesis ◽

Allylic Alcohols ◽

Samarium Diiodide ◽

Efficient Route

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Samarium Diiodide: A Mild and Selective Reagent in organic synthesis

Journal für praktische Chemie ◽

10.1002/prac.19973390120 ◽

1997 ◽

Vol 339 (1) ◽

pp. 101-104 ◽

Cited By ~ 13

Author(s):

Faiz Ahmed Khan ◽

Reinhold Zimmer

Keyword(s):

Organic Synthesis ◽

Samarium Diiodide ◽

Selective Reagent

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Direct methylenation of steroidal .alpha.,.beta.-epoxy ketones

The Journal of Organic Chemistry ◽

10.1021/jo01280a026 ◽

1967 ◽

Vol 32 (5) ◽

pp. 1409-1413 ◽

Cited By ~ 2

Author(s):

Ivar Laos

Keyword(s):

Alpha Beta ◽

Epoxy Ketones

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ChemInform Abstract: Lanthanoids in Organic Synthesis. Part 8. 1,3-Asymmetric Induction in Intramolecular Reformatsky-Type Reactions Promoted by Samarium Diiodide.

ChemInform ◽

10.1002/chin.198806089 ◽

1988 ◽

Vol 19 (6) ◽

Author(s):

G. A. MOLANDER ◽

J. B. ETTER

Keyword(s):

Organic Synthesis ◽

Asymmetric Induction ◽

Samarium Diiodide

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Lanthanides in organic synthesis. 9. Samarium diiodide promoted intramolecular pinacolic coupling reactions

The Journal of Organic Chemistry ◽

10.1021/jo00244a062 ◽

1988 ◽

Vol 53 (9) ◽

pp. 2132-2134 ◽

Cited By ~ 65

Author(s):

Gary A. Molander ◽

Caryn Kenny

Keyword(s):

Organic Synthesis ◽

Samarium Diiodide ◽

Coupling Reactions

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