Oxidative deamination of sec-alkyl primary amines with 3,5-di-tert-butyl-1,2-benzoquinone; a second look

1988 ◽  
Vol 53 (26) ◽  
pp. 5994-5998 ◽  
Author(s):  
Robert F. X. Klein ◽  
Lisa M. Bargas ◽  
Vaclav Horak
Keyword(s):  
Primary Amines ◽  
Oxidative Deamination ◽  
Tert Butyl ◽  
Second Look

A New Synthesis of Primary Amines Usingtert-Butylamine as an Ammonia Equivalent: The Triflic Acid Catalysed Removal ofN-tert-Butyl Groups from Carbamates

Synlett ◽  
1990 ◽  
Vol 1990 (10) ◽  
pp. 621-623 ◽  
Author(s):  
Martyn J. Earle ◽  
Robin A. Fairhurst ◽  
Harry Heaney ◽  
George Papageorgiou
Keyword(s):  
Primary Amines ◽  
Triflic Acid ◽  
Tert Butyl ◽  
New Synthesis

Attempted Oxidative Deamination ofN-Deacetylcolchicinoids with 3,5-Di(tert-butyl)-1,2-benzoquinone: Synthesis of 2H-1,4-Benzoxazine-Type Adducts

1999 ◽  
Vol 82 (9) ◽  
pp. 1502-1508 ◽  
Author(s):  
Bruno Danieli ◽  
Giordano Lesma ◽  
Daniele Passarella ◽  
Davide Prosperi ◽  
Alessandra Silvani ◽  
...  
Keyword(s):  
Oxidative Deamination ◽  
Tert Butyl

scholarly journals The Synthesis of Two Combinatorial Libraries Using a 4-(2-Thienyl)-pyrrole Template

2002 ◽  
Vol 55 (12) ◽  
pp. 789 ◽  
Author(s):  
Rohan A. Davis ◽  
Anthony R. Carroll ◽  
Ronald J. Quinn
Keyword(s):  
Reductive Amination ◽  
Combinatorial Libraries ◽  
Solution Phase ◽  
Primary Amines ◽  
The Novel ◽  
Compound Library ◽  
Phase Synthesis ◽  
Parallel Solution ◽  
Tert Butyl ◽  
Solution Phase Synthesis

The synthesis of the novel biaryl compound, 4-(2-thienyl)-1H-pyrrole-2-carbaldehyde (1), by Suzuki–Miyaura coupling conditions is reported. Compound (1) was subsequently used as a combinatorial template in the parallel solution-phase synthesis of an amine and imine compound library. The amine library was produced using reductive amination conditions, and purification was achieved by a liquid–liquid partition followed by silica chromatography to afford ten amine analogues. The imine library consisted of five compounds, which were synthesized using volatile primary amines that allowed purification by evaporation. The synthesis of the novel and related biaryl carbaldehyde, tert-butyl-2-(5-formyl-1H-pyrrol-3-yl)-1H-pyrrole-1-carboxylate (2) is also reported.

Oxidative Deamination of Various Primary Amines to the Corresponding Carbonyl Compounds by UsingN-tert-Butylphenylsulfinimidoyl Chloride

2001 ◽  
Vol 30 (7) ◽  
pp. 712-713 ◽  
Author(s):  
Jun-ichi Matsuo ◽  
Asahi Kawana ◽  
Yoshio Fukuda ◽  
Teruaki Mukaiyama
Keyword(s):  
Carbonyl Compounds ◽  
Primary Amines ◽  
Oxidative Deamination
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