Selectivity in the photochlorination of 2,3-dimethylbutane with molecular chlorine in noncomplexing solvents

1988 ◽  
Vol 53 (22) ◽  
pp. 5220-5225 ◽  
Author(s):  
K. D. Raner ◽  
J. Lusztyk ◽  
K. U. Ingold
Keyword(s):  
Molecular Chlorine

Ion‐assisted etching of silicon by molecular chlorine

1984 ◽  
Vol 2 (2) ◽  
pp. 487-491 ◽  
Author(s):  
F. H. M. Sanders ◽  
A. W. Kolfschoten ◽  
J. Dieleman ◽  
R. A. Haring ◽  
A. Haring ◽  
...  
Keyword(s):  
Molecular Chlorine

scholarly journals Oriented chlorine atoms as a probe of the nonadiabatic photodissociation dynamics of molecular chlorine

2000 ◽  
Vol 113 (20) ◽  
pp. 9022-9031 ◽  
Author(s):  
Andrew J. Alexander ◽  
Zee Hwan Kim ◽  
S. Alex Kandel ◽  
Richard N. Zare ◽  
T. Peter Rakitzis ◽  
...  
Keyword(s):  
Molecular Chlorine ◽  
Chlorine Atoms

Photoelectron studies of molecular chlorine using synchrotron radiation

1988 ◽  
Vol 120 (1) ◽  
pp. 149-154 ◽  
Author(s):  
T. Reddish ◽  
A.A. Cafolla ◽  
J. Comer
Keyword(s):  
Synchrotron Radiation ◽  
Molecular Chlorine

A facile synthesis of sulfonyl chlorides

1976 ◽  
Vol 54 (3) ◽  
pp. 498-499 ◽  
Author(s):  
Richard F. Langler
Keyword(s):  
Acetic Acid ◽  
Aqueous Acetic Acid ◽  
Sulfenyl Chloride ◽  
Molecular Chlorine ◽  
Facile Synthesis ◽  
Sulfonyl Chlorides

Benzylic sulfides have been shown to furnish sulfonyl chlorides in excellent yields, upon reaction with molecular chlorine in aqueous acetic acid. The reaction most likely proceeds through the intermediacy of the corresponding sulfenyl chloride.

scholarly journals Photoionisation Cross Sections of Chlorine Atoms and Molecules at 584 Å

1986 ◽  
Vol 39 (5) ◽  
pp. 779 ◽  
Author(s):  
WJ van der Meer ◽  
RJ Butselaar ◽  
CA de Lange
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Ground State ◽  
Modulation Method ◽  
Absolute Cross Section ◽  
Molecular Chlorine ◽  
Chlorine Atoms ◽  
Atoms And Molecules ◽  
Ionic States ◽  
State Ionic

A recently developed modulation method is used to obtain cross sections for the photoionisation of ground state neutral to ground state ionic, atomic and molecular chlorine relative to that of the HCl + (X2n 1IZ,3IZ) +-- HCl(XI ~ +) transition at the He Ia wavelength. With the known absolute cross section of the latter process, determined by (e,2e) coincidence spectroscopy, the present ell,periments provide absolute photoionisation cross sections of the CI + epz,l,o) +-- Clep) and Cli (XZ n g, 1IZ,3 IZ) +-- Clz (X I ~ t) transitions. Relative cross sections, previously determined for the transitions to the additional Cl and Clz ionic states accessible with He Ia radiation, are used to obtain absolute cross sections for the Cl+(IDz, ISO) +-- Clep) and Cli(AZnu,1IZ,3IZ, BZ~t) +-- Clz(XI~t) ionisation processes.

Monte Carlo simulation of chlorine adsorbed on graphite

1988 ◽  
Vol 66 (4) ◽  
pp. 955-962 ◽  
Author(s):  
Soong-Hyuck Suh ◽  
Seamus F. O'Shea
Keyword(s):  
Monte Carlo Simulation ◽  
Monte Carlo ◽  
Basal Plane ◽  
Thermodynamic Data ◽  
Molecular Chlorine ◽  
Monte Carlo Calculations ◽  
Structure And Dynamics ◽  
Wide Range ◽  
Do So ◽  
Molecule Surface

Monte Carlo calculations are reported for patches of molecular chlorine adsorbed on the basal plane of graphite. A variety of combinations of intermolecular and molecule–surface potentials have been tested, and the resulting structural predictions cover a wide range of behaviour. None of the combinations employed here can explain the recent experimental observations, but it is clear that at least some could be adjusted to do so. However, the lack of thermodynamic data concerning the interaction between the molecules and the surface presents a major obstacle. Further experiments which give information about the energetics of the system are needed before a definitive account of the structure and dynamics can be given.

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