A useful Wittig reagent for the stereoselective synthesis of trans-.alpha.,.beta.-unsaturated thiol esters

1985 ◽  
Vol 50 (5) ◽  
pp. 709-710 ◽  
Author(s):  
Gary E. Keck ◽  
Eugene P. Boden ◽  
Scott A. Mabury
1991 ◽  
Vol 69 (6) ◽  
pp. 934-936 ◽  
Author(s):  
Hsing-Jang Liu ◽  
Patricia A. Rose ◽  
Doug J. Sasaki

α,β-Unsaturated thiol esters could be readily prepared via a Wadsworth–Emmons reaction using diethyl alkylthiocarbonylmethylphosphonate, which proved to be superior in reactivity to the corresponding Wittig reagent. Key words: α,β-unsaturated thiol esters, Wadsworth–Emmons reaction.


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