Organoselenium-induced ring closures. Stereoselective synthesis of cyclic .alpha.,.beta.-unsaturated sulfoxides, sulfones, and sulfides and synthesis of 6,9-sulfoxa-5(E)- and -5(Z)-prostacyclin, 6,9-sulfo-5(E)- and -5(Z)-prostacyclin, 6,9-sulfo-6.alpha.- and -6.beta.-4(E)-isoprostacyclin, and 6,9-thiaprostacyclin

K. C. Nicolaou; W. E. Barnette; R. L. Magolda

doi:10.1021/ja00476a061

Organoselenium-induced ring closures. Stereoselective synthesis of cyclic .alpha.,.beta.-unsaturated sulfoxides, sulfones, and sulfides and synthesis of 6,9-sulfoxa-5(E)- and -5(Z)-prostacyclin, 6,9-sulfo-5(E)- and -5(Z)-prostacyclin, 6,9-sulfo-6.alpha.- and -6.beta.-4(E)-isoprostacyclin, and 6,9-thiaprostacyclin

Journal of the American Chemical Society ◽

10.1021/ja00476a061 ◽

1978 ◽

Vol 100 (8) ◽

pp. 2567-2570 ◽

Cited By ~ 32

Author(s):

K. C. Nicolaou ◽

W. E. Barnette ◽

R. L. Magolda

Keyword(s):

Stereoselective Synthesis ◽

Alpha Beta

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A stereoselective synthesis of (Z)- and (E)-trifluoromethylated .alpha.,.beta.-unsaturated esters via intramolecular Wittig reaction

The Journal of Organic Chemistry ◽

10.1021/jo00069a014 ◽

1993 ◽

Vol 58 (17) ◽

pp. 4564-4566 ◽

Cited By ~ 37

Author(s):

Yanchang Shen ◽

Shu Gao

Keyword(s):

Wittig Reaction ◽

Stereoselective Synthesis ◽

Unsaturated Esters ◽

Intramolecular Wittig Reaction ◽

Alpha Beta

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Stereoselective synthesis of tetrasubstituted .alpha.,.beta.-unsaturated esters

The Journal of Organic Chemistry ◽

10.1021/jo00035a043 ◽

1992 ◽

Vol 57 (9) ◽

pp. 2753-2755 ◽

Cited By ~ 8

Author(s):

Jacob Mathew

Keyword(s):

Stereoselective Synthesis ◽

Unsaturated Esters ◽

Alpha Beta

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A New Stereoselective Synthesis of (E)-.alpha.,.beta.-Unsaturated-.gamma.-dicarbonyl Compounds by the Henry Reaction

The Journal of Organic Chemistry ◽

10.1021/jo00097a061 ◽

1994 ◽

Vol 59 (18) ◽

pp. 5466-5467 ◽

Cited By ~ 29

Author(s):

Roberto Ballini ◽

Giovanna Bosica

Keyword(s):

Stereoselective Synthesis ◽

Henry Reaction ◽

Dicarbonyl Compounds ◽

Alpha Beta

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Stereoselective Synthesis of Highly Substituted .gamma.-Lactones and Butenolides by Intramolecular Michael Addition of Enantiomerically Enriched .gamma.-[(Phenylthio)acyl]oxy .alpha.,.beta.-Unsaturated Esters

The Journal of Organic Chemistry ◽

10.1021/jo00095a022 ◽

1994 ◽

Vol 59 (16) ◽

pp. 4461-4472 ◽

Cited By ~ 21

Author(s):

Carmen M. Rodriguez ◽

Tomas Martin ◽

Miguel A. Ramirez ◽

Victor S. Martin

Keyword(s):

Michael Addition ◽

Stereoselective Synthesis ◽

Unsaturated Esters ◽

Alpha Beta

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Reaction of allylstannanes with .alpha.,.beta.-unsaturated acyliron complexes: stereoselective synthesis of cyclopentane derivatives

Organometallics ◽

10.1021/om00162a030 ◽

1990 ◽

Vol 9 (12) ◽

pp. 3157-3171 ◽

Cited By ~ 23

Author(s):

James W. Herndon ◽

Chao Wu ◽

Jill J. Harp

Keyword(s):

Stereoselective Synthesis ◽

Alpha Beta

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Radical addition to carbonyl carbon promoted by aqueous titanium trichloride: stereoselective synthesis of .alpha.,.beta.-dihydroxy ketones

The Journal of Organic Chemistry ◽

10.1021/jo00277a025 ◽

1989 ◽

Vol 54 (16) ◽

pp. 3872-3878 ◽

Cited By ~ 28

Author(s):

Angelo Clerici ◽

Ombretta Porta

Keyword(s):

Stereoselective Synthesis ◽

Radical Addition ◽

Carbonyl Carbon ◽

Titanium Trichloride ◽

Alpha Beta

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Application of the .alpha.,.beta.-epoxy ketone photorearrangement to diterpene construction. Stereoselective synthesis of (.+-.)-4a.beta.,10.beta.-doladiol acetate

The Journal of Organic Chemistry ◽

10.1021/jo00375a011 ◽

1986 ◽

Vol 51 (25) ◽

pp. 4807-4813 ◽

Cited By ~ 23

Author(s):

Leo A. Paquette ◽

Ho Shen Lin ◽

Daniel T. Belmont ◽

James P. Springer

Keyword(s):

Stereoselective Synthesis ◽

Alpha Beta

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ChemInform Abstract: A Facile and Mild Approach for Stereoselective Synthesis of α-Fluoro-.alpha±beta.-unsaturated Esters from α-Fluoro-β-keto Esters via Deacylation.

ChemInform ◽

10.1002/chin.201523084 ◽

2015 ◽

Vol 46 (23) ◽

pp. no-no

Author(s):

Jinlong Qian ◽

Wenbin Yi ◽

Meifang Lv ◽

Chun Cai

Keyword(s):

Stereoselective Synthesis ◽

Unsaturated Esters ◽

Keto Esters ◽

Alpha Beta

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A useful Wittig reagent for the stereoselective synthesis of trans-.alpha.,.beta.-unsaturated thiol esters

The Journal of Organic Chemistry ◽

10.1021/jo00205a036 ◽

1985 ◽

Vol 50 (5) ◽

pp. 709-710 ◽

Cited By ~ 29

Author(s):

Gary E. Keck ◽

Eugene P. Boden ◽

Scott A. Mabury

Keyword(s):

Stereoselective Synthesis ◽

Thiol Esters ◽

Alpha Beta ◽

Wittig Reagent

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Stereoselective synthesis of trisubstituted .alpha.,.beta.-unsaturated esters and amides via reactions of tantalum-alkyne complexes derived from acetylenic esters and amides with carbonyl compounds

The Journal of Organic Chemistry ◽

10.1021/jo00021a005 ◽

1991 ◽

Vol 56 (21) ◽

pp. 5980-5982 ◽

Cited By ~ 20

Author(s):

Kazuhiko Takai ◽

Makoto Tezuka ◽

Kiitiro Utimoto

Keyword(s):

Carbonyl Compounds ◽

Stereoselective Synthesis ◽

Acetylenic Esters ◽

Unsaturated Esters ◽

Alpha Beta ◽

Alkyne Complexes

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