Kinetics of proton transfer of 3,5-heptanedione, 2,6-dimethyl-3,5-heptanedione, and dibenzoylmethane with amines in 50% dimethyl sulfoxide-50% water. Effect of steric crowding and .pi.-overlap on intrinsic rate constants

Claude F. Bernasconi; Douglas A. A. Ohlberg; Michael W. Stronach

doi:10.1021/jo00009a017

Kinetics of proton transfer of 3,5-heptanedione, 2,6-dimethyl-3,5-heptanedione, and dibenzoylmethane with amines in 50% dimethyl sulfoxide-50% water. Effect of steric crowding and .pi.-overlap on intrinsic rate constants

The Journal of Organic Chemistry ◽

10.1021/jo00009a017 ◽

1991 ◽

Vol 56 (9) ◽

pp. 3016-3020 ◽

Cited By ~ 8

Author(s):

Claude F. Bernasconi ◽

Douglas A. A. Ohlberg ◽

Michael W. Stronach

Keyword(s):

Proton Transfer ◽

Dimethyl Sulfoxide ◽

Rate Constants ◽

Intrinsic Rate ◽

Water Effect ◽

Steric Crowding ◽

Kinetics Of

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Kinetics of hydroxide and nitromethide ion addition to substituted .beta.-nitrostyrenes in dimethyl sulfoxide-water mixtures. Solvent dependence of .pi.-donor substituent effects and of intrinsic rate constants

The Journal of Organic Chemistry ◽

10.1021/jo00030a019 ◽

1992 ◽

Vol 57 (4) ◽

pp. 1132-1139 ◽

Cited By ~ 3

Author(s):

Claude F. Bernasconi ◽

Janie L. Zitomer ◽

David F. Schuck

Keyword(s):

Dimethyl Sulfoxide ◽

Rate Constants ◽

Substituent Effects ◽

Intrinsic Rate ◽

Solvent Dependence ◽

Kinetics Of ◽

Donor Substituent

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Kinetics of Proton Transfer from Cationic Carbon Acids in Water and Aqueous DMSO. Effect of Activating Groups and Solvent on Intrinsic Rate Constants

The Journal of Organic Chemistry ◽

10.1021/jo051166r ◽

2005 ◽

Vol 70 (19) ◽

pp. 7721-7730 ◽

Cited By ~ 3

Author(s):

Claude F. Bernasconi ◽

Douglas E. Fairchild ◽

Robert L. Montañez ◽

Perdram Aleshi ◽

Huaiben Zheng ◽

...

Keyword(s):

Proton Transfer ◽

Rate Constants ◽

Intrinsic Rate ◽

Aqueous Dmso ◽

Carbon Acids ◽

Kinetics Of

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ChemInform Abstract: Kinetics of Proton Transfer from 2-Nitro-4-X-phenylacetonitriles to Piperidine and Morpholine in Aqueous Me2SO. Solvent and Substituent Effects on Intrinsic Rate Constants. Transition State Imbalances.

ChemInform ◽

10.1002/chin.199711048 ◽

2010 ◽

Vol 28 (11) ◽

pp. no-no

Author(s):

C. F. BERNASCONI ◽

P. J. WENZEL

Keyword(s):

Proton Transfer ◽

Transition State ◽

Rate Constants ◽

Substituent Effects ◽

Intrinsic Rate ◽

Kinetics Of

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Kinetics of deprotonation of triphenyl(2-substituted-9-fluorenyl)phosphonium ions in 50% dimethyl sulfoxide-50% water. Intrinsic rate constants, imbalances and evidence for changes in transition state structure

Journal of Physical Organic Chemistry ◽

10.1002/poc.610050705 ◽

1992 ◽

Vol 5 (7) ◽

pp. 409-423 ◽

Cited By ~ 1

Author(s):

Claude F. Bernasconi ◽

Douglas E. Fairchild

Keyword(s):

Transition State ◽

Dimethyl Sulfoxide ◽

Rate Constants ◽

Intrinsic Rate ◽

State Structure ◽

Transition State Structure ◽

Kinetics Of

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Kinetics of Proton Transfer from 2-Nitro-4-X-phenylacetonitriles to Piperidine and Morpholine in Aqueous Me2SO. Solvent and Substituent Effects on Intrinsic Rate Constants. Transition State Imbalances

Journal of the American Chemical Society ◽

10.1021/ja961837q ◽

1996 ◽

Vol 118 (46) ◽

pp. 11446-11453 ◽

Cited By ~ 14

Author(s):

Claude F. Bernasconi ◽

Philip J. Wenzel

Keyword(s):

Proton Transfer ◽

Transition State ◽

Rate Constants ◽

Substituent Effects ◽

Intrinsic Rate ◽

Kinetics Of

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Kinetics of Proton Transfer from Benzoylnitromethane and 1,2-Diphenyl-2-nitroethanone to Various Bases. Resonance, Inductive, Solvation, Steric, and Transition State Hydrogen-Bonding Effects on Intrinsic Rate Constants

The Journal of Organic Chemistry ◽

10.1021/jo971259b ◽

1997 ◽

Vol 62 (23) ◽

pp. 8162-8170 ◽

Cited By ~ 10

Author(s):

Claude F. Bernasconi ◽

Robert L. Montañez

Keyword(s):

Hydrogen Bonding ◽

Proton Transfer ◽

Transition State ◽

Rate Constants ◽

Intrinsic Rate ◽

Kinetics Of

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ChemInform Abstract: Kinetics of Deprotonation of Arylnitromethanes by Benzoate Ions in Acetonitrile Solution. Effect of Equilibrium and Nonequilibrium Transition-State Solvation on Intrinsic Rate Constants of Proton Transfers

ChemInform ◽

10.1002/chin.199220042 ◽

2010 ◽

Vol 23 (20) ◽

pp. no-no

Author(s):

J. R. GANDLER ◽

C. F. BERNASCONI

Keyword(s):

Transition State ◽

Rate Constants ◽

Intrinsic Rate ◽

Acetonitrile Solution ◽

Proton Transfers ◽

Kinetics Of

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ChemInform Abstract: Nucleophilic Addition to Olefins. Part 25. Kinetics of Hydrolysis of Substituted β-Nitrostyrenes. Transition-State Imbalances and Intrinsic Rate Constants for Three Different Types of Nitronate Ion Forming Processes. Relevance to the

ChemInform ◽

10.1002/chin.198944081 ◽

1989 ◽

Vol 20 (44) ◽

Author(s):

C. F. BERNASCONI ◽

P. PASCHALIS

Keyword(s):

Transition State ◽

Rate Constants ◽

Nucleophilic Addition ◽

Intrinsic Rate ◽

Kinetics Of Hydrolysis ◽

Different Types ◽

Kinetics Of ◽

Hydrolysis Of

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Kinetics of proton transfer from tetra(m-trifluoromethylphenyl)dibenzotetraazaporphin to nitrogen-containing bases in a benzene-dimethyl sulfoxide system

Russian Journal of Physical Chemistry A ◽

10.1134/s003602441502020x ◽

2014 ◽

Vol 89 (2) ◽

pp. 196-201 ◽

Cited By ~ 2

Author(s):

O. A. Petrov

Keyword(s):

Proton Transfer ◽

Dimethyl Sulfoxide ◽

Kinetics Of

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ChemInform Abstract: Kinetics of Amine Addition to Benzylidene-1,3-indandione and Other Vinylic β-Diketones. Effect of Cyclic Structure and Steric Strain on Intrinsic Rate Constants.

ChemInform ◽

10.1002/chin.199129060 ◽

2010 ◽

Vol 22 (29) ◽

pp. no-no

Author(s):

C. F. BERNASCONI ◽

M. W. STRONACH

Keyword(s):

Rate Constants ◽

Intrinsic Rate ◽

Cyclic Structure ◽

Steric Strain ◽

Amine Addition ◽

Kinetics Of

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