Kinetics of deprotonation of triphenyl(2-substituted-9-fluorenyl)phosphonium ions in 50% dimethyl sulfoxide-50% water. Intrinsic rate constants, imbalances and evidence for changes in transition state structure

Claude F. Bernasconi; Douglas E. Fairchild

doi:10.1002/poc.610050705

Kinetics of deprotonation of triphenyl(2-substituted-9-fluorenyl)phosphonium ions in 50% dimethyl sulfoxide-50% water. Intrinsic rate constants, imbalances and evidence for changes in transition state structure

Journal of Physical Organic Chemistry ◽

10.1002/poc.610050705 ◽

1992 ◽

Vol 5 (7) ◽

pp. 409-423 ◽

Cited By ~ 1

Author(s):

Claude F. Bernasconi ◽

Douglas E. Fairchild

Keyword(s):

Transition State ◽

Dimethyl Sulfoxide ◽

Rate Constants ◽

Intrinsic Rate ◽

State Structure ◽

Transition State Structure ◽

Kinetics Of

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ChemInform Abstract: Kinetics of Deprotonation of Arylnitromethanes by Benzoate Ions in Acetonitrile Solution. Effect of Equilibrium and Nonequilibrium Transition-State Solvation on Intrinsic Rate Constants of Proton Transfers

ChemInform ◽

10.1002/chin.199220042 ◽

2010 ◽

Vol 23 (20) ◽

pp. no-no

Author(s):

J. R. GANDLER ◽

C. F. BERNASCONI

Keyword(s):

Transition State ◽

Rate Constants ◽

Intrinsic Rate ◽

Acetonitrile Solution ◽

Proton Transfers ◽

Kinetics Of

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ChemInform Abstract: Nucleophilic Addition to Olefins. Part 25. Kinetics of Hydrolysis of Substituted β-Nitrostyrenes. Transition-State Imbalances and Intrinsic Rate Constants for Three Different Types of Nitronate Ion Forming Processes. Relevance to the

ChemInform ◽

10.1002/chin.198944081 ◽

1989 ◽

Vol 20 (44) ◽

Author(s):

C. F. BERNASCONI ◽

P. PASCHALIS

Keyword(s):

Transition State ◽

Rate Constants ◽

Nucleophilic Addition ◽

Intrinsic Rate ◽

Kinetics Of Hydrolysis ◽

Different Types ◽

Kinetics Of ◽

Hydrolysis Of

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Kinetics of hydroxide and nitromethide ion addition to substituted .beta.-nitrostyrenes in dimethyl sulfoxide-water mixtures. Solvent dependence of .pi.-donor substituent effects and of intrinsic rate constants

The Journal of Organic Chemistry ◽

10.1021/jo00030a019 ◽

1992 ◽

Vol 57 (4) ◽

pp. 1132-1139 ◽

Cited By ~ 3

Author(s):

Claude F. Bernasconi ◽

Janie L. Zitomer ◽

David F. Schuck

Keyword(s):

Dimethyl Sulfoxide ◽

Rate Constants ◽

Substituent Effects ◽

Intrinsic Rate ◽

Solvent Dependence ◽

Kinetics Of ◽

Donor Substituent

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Transition state structure, energetics, and rate constants for the CH4+F(2P)→CH3+HF reaction

Chemical Physics ◽

10.1016/j.chemphys.2005.01.032 ◽

2005 ◽

Vol 315 (1-2) ◽

pp. 27-34 ◽

Cited By ~ 16

Author(s):

Orlando Roberto-Neto ◽

Francisco B.C. Machado ◽

Fernando R. Ornellas

Keyword(s):

Transition State ◽

Rate Constants ◽

State Structure ◽

Transition State Structure

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Kinetics of deprotonation of arylnitromethanes by benzoate ions in acetonitrile solution. Effect of equilibrium and nonequilibrium transition state solvation on intrinsic rate constants of proton transfers

Journal of the American Chemical Society ◽

10.1021/ja00028a032 ◽

1992 ◽

Vol 114 (2) ◽

pp. 631-637 ◽

Cited By ~ 20

Author(s):

Joseph R. Gandler ◽

Claude F. Bernasconi

Keyword(s):

Transition State ◽

Rate Constants ◽

Intrinsic Rate ◽

Acetonitrile Solution ◽

Proton Transfers ◽

Kinetics Of

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Kinetics of proton transfer of 3,5-heptanedione, 2,6-dimethyl-3,5-heptanedione, and dibenzoylmethane with amines in 50% dimethyl sulfoxide-50% water. Effect of steric crowding and .pi.-overlap on intrinsic rate constants

The Journal of Organic Chemistry ◽

10.1021/jo00009a017 ◽

1991 ◽

Vol 56 (9) ◽

pp. 3016-3020 ◽

Cited By ~ 8

Author(s):

Claude F. Bernasconi ◽

Douglas A. A. Ohlberg ◽

Michael W. Stronach

Keyword(s):

Proton Transfer ◽

Dimethyl Sulfoxide ◽

Rate Constants ◽

Intrinsic Rate ◽

Water Effect ◽

Steric Crowding ◽

Kinetics Of

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Transition state structure, energetics, and rate constants for the F (2P)+C2H6→C2H5+HF reaction

Chemical Physics Letters ◽

10.1016/j.cplett.2007.10.064 ◽

2007 ◽

Vol 449 (1-3) ◽

pp. 67-71 ◽

Cited By ~ 1

Author(s):

Orlando Roberto-Neto ◽

Francisco B.C. Machado

Keyword(s):

Transition State ◽

Rate Constants ◽

State Structure ◽

Transition State Structure

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ChemInform Abstract: Kinetics of Proton Transfer from 2-Nitro-4-X-phenylacetonitriles to Piperidine and Morpholine in Aqueous Me2SO. Solvent and Substituent Effects on Intrinsic Rate Constants. Transition State Imbalances.

ChemInform ◽

10.1002/chin.199711048 ◽

2010 ◽

Vol 28 (11) ◽

pp. no-no

Author(s):

C. F. BERNASCONI ◽

P. J. WENZEL

Keyword(s):

Proton Transfer ◽

Transition State ◽

Rate Constants ◽

Substituent Effects ◽

Intrinsic Rate ◽

Kinetics Of

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Nucleophilic addition to olefins. Part 25. Kinetics of hydrolysis of substituted .beta.-nitrostyrenes. Transition-state imbalances and intrinsic rate constants for three different types of nitronate ion forming processes. Relevance to the nitroalkane anomaly

Journal of the American Chemical Society ◽

10.1021/ja00197a059 ◽

1989 ◽

Vol 111 (15) ◽

pp. 5893-5902 ◽

Cited By ~ 12

Author(s):

Claude F. Bernasconi ◽

Peter Paschalis

Keyword(s):

Transition State ◽

Rate Constants ◽

Nucleophilic Addition ◽

Intrinsic Rate ◽

Kinetics Of Hydrolysis ◽

Different Types ◽

Kinetics Of ◽

Hydrolysis Of

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Kinetics of Proton Transfer from 2-Nitro-4-X-phenylacetonitriles to Piperidine and Morpholine in Aqueous Me2SO. Solvent and Substituent Effects on Intrinsic Rate Constants. Transition State Imbalances

Journal of the American Chemical Society ◽

10.1021/ja961837q ◽

1996 ◽

Vol 118 (46) ◽

pp. 11446-11453 ◽

Cited By ~ 14

Author(s):

Claude F. Bernasconi ◽

Philip J. Wenzel

Keyword(s):

Proton Transfer ◽

Transition State ◽

Rate Constants ◽

Substituent Effects ◽

Intrinsic Rate ◽

Kinetics Of

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