Liquid−Liquid Equilibrium for Systems of Canola Oil, Oleic Acid, and Short-Chain Alcohols

1999 ◽  
Vol 44 (6) ◽  
pp. 1360-1364 ◽  
Author(s):  
Eduardo Batista ◽  
Sandra Monnerat ◽  
Kênia Kato ◽  
Luiz Stragevitch ◽  
Antonio J. A. Meirelles
Keyword(s):  
Oleic Acid ◽  
Canola Oil ◽  
Short Chain ◽  
Liquid Equilibrium

Liquid−Liquid Equilibrium Data for Fatty Systems Containing Refined Rice Bran Oil, Oleic Acid, Anhydrous Ethanol, and Hexane

2009 ◽  
Vol 54 (8) ◽  
pp. 2174-2181 ◽  
Author(s):  
Wagner L. Priamo ◽  
Marcelo Lanza ◽  
Antonio J. A. Meirelles ◽  
Eduardo A. C. Batista
Keyword(s):  
Oleic Acid ◽  
Rice Bran ◽  
Rice Bran Oil ◽  
Anhydrous Ethanol ◽  
Liquid Equilibrium ◽  
Equilibrium Data

Alcoholysis of canola oil using a short-chain (C1–C3) alcohols

2014 ◽  
Vol 20 (5) ◽  
pp. 3689-3694 ◽  
Author(s):  
In Kwon Hong ◽  
Jung Woo Park ◽  
Hyungjin Kim ◽  
Seung Bum Lee
Keyword(s):  
Canola Oil ◽  
Short Chain

Liquid−Liquid Equilibrium Data for the System Corn Oil + Oleic Acid + Ethanol + Water at 298.15 K

2002 ◽  
Vol 47 (3) ◽  
pp. 416-420 ◽  
Author(s):  
Cintia B. Gonçalves ◽  
Eduardo Batista ◽  
Antonio J. A. Meirelles
Keyword(s):  
Oleic Acid ◽  
Corn Oil ◽  
Liquid Equilibrium ◽  
Equilibrium Data

scholarly journals NMR Spectroscopic Study of Chemical Reactions in Mixtures Containing Oleic Acid, Formic Acid, and Formoxystearic Acid

2021 ◽  
Author(s):  
Agnes Fröscher ◽  
Kai Langenbach ◽  
Erik von Harbou ◽  
Werner R. Thiel ◽  
Hans Hasse
Keyword(s):  
Oleic Acid ◽  
Nmr Spectroscopy ◽  
Formic Acid ◽  
Chemical Reactions ◽  
Elaidic Acid ◽  
Renewable Resources ◽  
Reactive System ◽  
Liquid Equilibrium ◽  
Reactive Liquid ◽  
Potential Precursor

Oleic acid (OA) and formic acid (FA) react to formoxystearic acid (FSA), in the presence of acidic catalysts.This reaction is of interest as OA can be obtained from renewable resources and FSA is a potential precursor for biopolymers.We have recently studied the liquid−liquid equilibrium (LLE) in the uncatalyzed nonreacting system OA + FA + FSA. Thiswork is extended here to the reactive system, in which a reactive liquid−liquid equilibrium (RLLE) exists. The reactionequilibrium is studied by quantitative NMR spectroscopy at temperatures between 333 and 353 K in homogeneous OA-richmixtures. This information is combined with that on the LLE to determine the RLLE. The physicochemical equilibria aremodeled in a thermodynamically consistent way using the associating lattice cluster theory (ALCT). Furthermore, data on thechemical equilibrium of the formation of the OA-isomer elaidic acid (EA) is supplied. Also the decomposition of FA and theformation of estolides (EL), which are oligomers of OA and EA, was observed and quantified.

Abstract P382: Canola and High-Oleic Acid Canola Oils Improve Lipid/Lipoprotein Parameters Compared to an Oil Blend Characteristic of a Western Dietary Pattern in Individuals at Risk for Metabolic Syndrome: A Randomized Crossover Clinical Trial

Circulation ◽  
2018 ◽  
Vol 137 (suppl_1) ◽  
Author(s):  
Kate J Bowen ◽  
Penny M Kris-Etherton ◽  
Sheila G West ◽  
Jennifer A Fleming ◽  
Philip W Connelly ◽  
...  
Keyword(s):  
Metabolic Syndrome ◽  
Clinical Trial ◽  
Fatty Acids ◽  
Oleic Acid ◽  
Canola Oil ◽  
Density Lipoprotein ◽  
High Oleic Acid ◽  
High Oleic ◽  
Oil Blend ◽  
Canola Oils

Introduction: Identifying dietary interventions for cardiometabolic disease prevention in individuals with metabolic syndrome is relevant to a significant portion of the population. Numerous studies have investigated the effects of canola oil on cardiovascular disease risk; however, no studies have compared canola oil diets to a control diet with a fatty acid composition characteristic of Western intakes in individuals with metabolic syndrome risk factors. The objectives of this study were to evaluate effects of canola oil, high-oleic acid canola oil (HOCO), and a control oil (blend of butter, safflower, coconut, and flaxseed oils formulated to represent a Western diet fatty acid profile) on lipids, lipoproteins, and apolipoproteins. Hypothesis: We tested the hypothesis that the two canola oil diets would elicit beneficial effects on the total lipid/lipoprotein profile compared to the Western (control oil) diet. Methods: In a multi-center, double blind, randomized, three-period crossover, controlled feeding clinical trial, 119 individuals with an increased waist circumference plus at least one additional metabolic syndrome risk factor consumed prepared isocaloric, weight maintenance diets containing canola oil [17.5% E from monounsaturated fatty acids (MUFA), 9.2% polyunsaturated fatty acids (PUFA), 6.6% saturated fatty acids (SFA)], HOCO (19.1% E from MUFA, 7.0% PUFA, 6.4% SFA), or control oil (11% E from MUFA, 10% PUFA, 12% SFA) for six-weeks each separated by 4-12 week washouts. The differences at the end of 42 days of feeding were tested. Results: The canola oil and HOCO resulted in lower endpoint total cholesterol (TC), low-density lipoprotein-cholesterol (LDL-C), the TC: high-density lipoprotein-cholesterol (HDL-C) ratio, apolipoprotein (apo) B, the apoB: apoA1 ratio, and non-HDL-C compared to control oil ( P <0.0001 for treatment effect), with no differences between HOCO and canola oil for these parameters. Endpoint apoA1 did not significantly differ between the two canola oils and control, but was higher after the HOCO compared to canola oil (1.46 ± 0.02 g/L vs. 1.43 ± 0.02 g/L, P = 0.0462). There were no differences among the three diets in endpoint triglycerides or HDL-C. Conclusions: Incorporating canola or high-oleic acid canola oils into the diet improves blood lipids and lipoproteins compared to a contemporary Western diet in individuals with at least two criteria for metabolic syndrome.

scholarly journals Diets Enriched with Conventional or High-Oleic Acid Canola Oils Lower Atherogenic Lipids and Lipoproteins Compared to a Diet with a Western Fatty Acid Profile in Adults with Central Adiposity

2019 ◽  
Vol 149 (3) ◽  
pp. 471-478 ◽  
Author(s):  
Kate J Bowen ◽  
Penny M Kris-Etherton ◽  
Sheila G West ◽  
Jennifer A Fleming ◽  
Philip W Connelly ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Oleic Acid ◽  
Canola Oil ◽  
Unsaturated Fatty Acids ◽  
Disease Risk ◽  
Hdl Cholesterol ◽  
Central Adiposity ◽  
High Oleic Acid ◽  
High Oleic ◽  
Lipids And Lipoproteins

ABSTRACTBackgroundNovel oils high in monounsaturated fatty acids (MUFAs) and low in saturated fatty acids (SFAs) are an alternative to partially hydrogenated oils high in trans-unsaturated fatty acids. There is widespread use of high-MUFA oils across the food industry; however, limited knowledge of their cardiovascular impact exists.ObjectivesWe investigated the effects of diets containing canola oil, high-oleic acid canola oil (HOCO), and a control oil blend (diet formulated to emulate a Western fat profile) on lipids, lipoproteins, and apolipoproteins (apos), as secondary outcomes of the trial.MethodsIn a multi-center, double-blind, randomized, 3-period crossover, controlled feeding trial, men (n = 44) and women (n = 75) with a mean age of 44 y, mean body mass index (BMI; in kg/m2) of 31.7, and an increased waist circumference plus ≥1 metabolic syndrome criteria consumed prepared, weight-maintenance diets containing canola oil [17.5% MUFAs, 9.2% polyunsaturated fatty acids (PUFAs), 6.6% SFAs], HOCO (19.1% MUFAs, 7.0% PUFAs, 6.4% SFAs), or control oil (10.5% MUFAs, 10.0% PUFAs, 12.3% SFAs) for 6 wk with ≥4-wk washouts. Fasting serum lipids were assessed at baseline and 6 wk. Diet effects were examined using a repeated measures mixed model.ResultsCompared with the control, canola and HOCO diets resulted in lower endpoint total cholesterol (TC; −4.2% and −3.4%; P < 0.0001), LDL cholesterol (−6.6% and −5.6%; P < 0.0001), apoB (−3.7% and −3.4%; P = 0.002), and non-HDL cholesterol (−4.5% and −4.0%; P = 0.001), with no differences between canola diets. The TC:HDL cholesterol and apoB:apoA1 ratios were lower after the HOCO diet than after the control diet (−3.7% and −3.4%, respectively). There were no diet effects on triglyceride, HDL cholesterol, or apoA1 concentrations.ConclusionsHOCO, with increased MUFAs at the expense of decreased PUFAs, elicited beneficial effects on lipids and lipoproteins comparable to conventional canola oil and consistent with reduced cardiovascular disease risk in adults with central adiposity. This trial was registered at www.clinicaltrials.gov as NCT02029833.

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