Liquid-Liquid Equilibrium Relations in Systems Involving Oleic Acid.

Author(s):  
N. L. Sample ◽  
C. O. Bennett ◽  
D. E. Holcomb
2009 ◽  
Vol 54 (8) ◽  
pp. 2174-2181 ◽  
Author(s):  
Wagner L. Priamo ◽  
Marcelo Lanza ◽  
Antonio J. A. Meirelles ◽  
Eduardo A. C. Batista

2002 ◽  
Vol 47 (3) ◽  
pp. 416-420 ◽  
Author(s):  
Cintia B. Gonçalves ◽  
Eduardo Batista ◽  
Antonio J. A. Meirelles

2021 ◽  
Author(s):  
Agnes Fröscher ◽  
Kai Langenbach ◽  
Erik von Harbou ◽  
Werner R. Thiel ◽  
Hans Hasse

Oleic acid (OA) and formic acid (FA) react to formoxystearic acid (FSA), in the presence of acidic catalysts.This reaction is of interest as OA can be obtained from renewable resources and FSA is a potential precursor for biopolymers.We have recently studied the liquid−liquid equilibrium (LLE) in the uncatalyzed nonreacting system OA + FA + FSA. Thiswork is extended here to the reactive system, in which a reactive liquid−liquid equilibrium (RLLE) exists. The reactionequilibrium is studied by quantitative NMR spectroscopy at temperatures between 333 and 353 K in homogeneous OA-richmixtures. This information is combined with that on the LLE to determine the RLLE. The physicochemical equilibria aremodeled in a thermodynamically consistent way using the associating lattice cluster theory (ALCT). Furthermore, data on thechemical equilibrium of the formation of the OA-isomer elaidic acid (EA) is supplied. Also the decomposition of FA and theformation of estolides (EL), which are oligomers of OA and EA, was observed and quantified.


1999 ◽  
Vol 44 (6) ◽  
pp. 1360-1364 ◽  
Author(s):  
Eduardo Batista ◽  
Sandra Monnerat ◽  
Kênia Kato ◽  
Luiz Stragevitch ◽  
Antonio J. A. Meirelles

2008 ◽  
Vol 53 (7) ◽  
pp. 1492-1497 ◽  
Author(s):  
Guilherme Sanaiotti ◽  
Jane Sélia R. Coimbra ◽  
José Carlos Gomes ◽  
Luis Antônio Minim

2010 ◽  
Vol 55 (7) ◽  
pp. 2416-2423 ◽  
Author(s):  
César A. S. da Silva ◽  
Guilherme Sanaiotti ◽  
Marcelo Lanza ◽  
Antonio J. A. Meirelles ◽  
Eduardo A. C. Batista

2017 ◽  
Vol 62 (9) ◽  
pp. 2855-2860 ◽  
Author(s):  
Leandro Ferreira-Pinto ◽  
Andreia Zanette ◽  
Fernando Augusto Pedersen Voll ◽  
Vladimir Ferreira Cabral ◽  
Marcelo Castier ◽  
...  

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