Vapor−Liquid Equilibria, Excess Molar Enthalpies, and Excess Molar Volumes of Dialkyl Carbonates + Methyltert-Butyl Ether at 298.15 K

1997 ◽  
Vol 42 (4) ◽  
pp. 697-701 ◽  
Author(s):  
Romolo Francesconi ◽  
Fabio Comelli
Keyword(s):  
Excess Molar Volumes ◽  
Excess Molar Enthalpies ◽  
Butyl Ether ◽  
Molar Volumes ◽  
Dialkyl Carbonates ◽  
Vapor Liquid Equilibria ◽  
Vapor Liquid

Excess molar volumes and isothermal vapor-liquid equilibria in the tetrahydrofuran with propan-1-ol and propan-2-ol systems at 298.15 K

1997 ◽  
Vol 75 (2) ◽  
pp. 207-211 ◽  
Author(s):  
Julio A. Salas ◽  
Eleuterio L. Arancibia ◽  
Miguel Katz
Keyword(s):  
Activity Coefficients ◽  
Chemical Species ◽  
Excess Molar Volumes ◽  
Experimental Results ◽  
Free Energies ◽  
Molar Volumes ◽  
Two Systems ◽  
Vapor Liquid Equilibria ◽  
Vapor Liquid

Densities and vapor-liquid equilibria were determined for tetrahydrofuran with propan-1-ol and propan-2-ol systems at 298.15 K. From the experimental results, excess molar volumes and excess Gibbs free energies were calculated. Information could be obtained from the possible interaction between both chemical species in the two systems. The Prigogine–Flory–Patterson method was applied to calculate excess molar volumes. Liquid activity coefficients were calculated and correlated with different expressions existing in the literature. Keywords: excess molar volumes, vapor–liquid equilibria, activity coefficients, excess Gibbs free energies, tetrahydrofuran, propan-1-ol, propan-2-ol.

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