Heat Capacities of Binary Mixtures of Acetic Acid with Acetic Anhydride and Methenamine at Different Temperatures

2010 ◽  
Vol 55 (4) ◽  
pp. 1704-1707 ◽  
Author(s):  
Li-Yan Dai ◽  
Qian Li ◽  
Ming Lei ◽  
Ying-Qi Chen
Keyword(s):  
Acetic Acid ◽  
Acetic Anhydride ◽  
Binary Mixtures ◽  
Heat Capacities ◽  
Different Temperatures

Kinematic viscosities of acetone, vinyl acetate, crotonaldehyde, acetic acid, acetic anhydride and their binary and ternary mixtures

1983 ◽  
Vol 48 (12) ◽  
pp. 3508-3516
Author(s):  
Pavol Škubla ◽  
Walter Waradzin
Keyword(s):  
Acetic Acid ◽  
Acetic Anhydride ◽  
Temperature Dependence ◽  
Vinyl Acetate ◽  
Binary Mixtures ◽  
Ternary Mixtures ◽  
Exponential Form ◽  
Binary And Ternary Mixtures

Kinematic viscosities of acetone, vinyl acetate, crotonaldehyde, acetic acid, acetic anhydride, their binary mixtures and two ternary mixtures (acetone-vinyl acetate-acetic acid and vinyl acetate-acetic acid-acetic anhydride) were measured. The values of coefficients of the Linke, McAllister, and Chandramouli-Laddha equations were calculated. The temperature dependence of the coefficients of last two equations can be expressed in terms of a function in exponential form, coefficients of which are tabulated.

Revisiting Glycerol Esterification with Acetic Acid over Amberlyst-35 via Statistically Designed Experiments: Overcoming Transport Limitations

2019 ◽  
Author(s):  
Víctor Gabriel Baldovino Medrano ◽  
Karen V. Caballero ◽  
Hernando Guerrero-Amaya
Keyword(s):  
Acetic Acid ◽  
Active Sites ◽  
Batch Reactor ◽  
Catalyst Particle ◽  
Experimental Designs ◽  
Particle Sizes ◽  
Turnover Rates ◽  
Designed Experiments ◽  
Different Temperatures ◽  
Glycerol Esterification

Turnover rates for glycerol esterification with acetic acid over Amberlyst-35 were measured under different temperatures, reactants and active sites concentrations, and catalyst particle sizes. Data were collected in a batch reactor. Experiments were done following a sequence of factorial experimental designs.

An unusual reaction of a bridged triterpenoid α-diketone with acetic anhydride

1991 ◽  
Vol 56 (12) ◽  
pp. 2917-2935 ◽  
Author(s):  
Eva Klinotová ◽  
Václav Křeček ◽  
Jiří Klinot ◽  
Miloš Buděšínský ◽  
Jaroslav Podlaha ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Nmr Spectroscopy ◽  
Acetic Anhydride ◽  
Spectral Methods ◽  
X Ray Diffraction ◽  
X Ray ◽  
Mild Conditions ◽  
Condensation Products ◽  
Unsaturated Lactones ◽  
C Nmr

3β-Acetoxy-21,22-dioxo-18α,19βH-ursan-28,20β-olide (IIIa) reacts with acetic anhydride in pyridine under very mild conditions affording β-lactone IVa and γ-lactones Va and VIIa as condensation products. On reaction with pyridine, lactones Va and VIIa undergo elimination of acetic acid to give unsaturated lactones VIIIa and IXa, respectively. Similarly, the condensation of 20β,28-epoxy-21,22-dioxo-18α,19βH-ursan-3β-yl acetate (IIIb) with acetic anhydride leads to β-lactone IVb and γ-lactone Vb; the latter on heating with pyridine affords unsaturated lactone VIIIb and 21-methylene-22-ketone Xb. The structure of the obtained compounds was derived using spectral methods, particularly 1H and 13C NMR spectroscopy; structure of lactone IVa was confirmed by X-ray diffraction.

scholarly journals Kinetics and Mechanism of the Change of the 4-Nitrobenzylthio-System into 4,4′-Diformylazoxybenzene in Alkaline Dioxane-Water Media

1985 ◽  
Vol 40 (11) ◽  
pp. 1128-1132
Author(s):  
Y. Riad ◽  
Adel N. Asaad ◽  
G.-A. S. Gohar ◽  
A. A. Abdallah
Keyword(s):  
Acetic Acid ◽  
Sodium Hydroxide ◽  
Rate Constants ◽  
Main Product ◽  
Reaction Medium ◽  
Aqueous Dioxane ◽  
Proton Abstraction ◽  
First Order ◽  
Water Media ◽  
Different Temperatures

Sodium hydroxide reacts with α -(4-nitrobenzylthio)-acetic acid in aqueous-dioxane media to give 4,4'-diformylazoxybenzene as the main product besides 4,4'-dicarboxyazoxybenzene and a nitrone acid. This reaction was kinetically studied in presence of excess of alkali in different dioxane-water media at different temperatures. It started by a fast reversible a-proton abstraction step followed by two consecutive irreversible first-order steps forming two intermediates (α -hydroxy, 4-nitrosobenzylthio)-acetic acid and 4-nitrosobenzaldehyde. The latter underwent a Cannizzaro's reaction, the products of which changed in the reaction medium into 4,4'-diformylazoxybenzene and 4,4'-dicarboxyazoxybenzene. The rate constants and the thermodynamic parameters of the two consecutive steps were calculated and discussed. A mechanism was put forward for the formation of the nitrone acid.Other six 4-nitrobenzyl, aryl sulphides were qualitatively studied and they gave mainly 4,4'-diformylazoxybenzene beside 4,4'-dicarboxyazoxybenzene or its corresponding azo acid.

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