Ability of the Ion-Selective Electrode in the Thermodynamic Modeling of the Mixed Electrolyte System: The Case of the Ternary NH4Cl + KCl + H2O Mixed Electrolyte Systems

Titration of sulphates with lead perchlorate employing lead ion selective electrode indication was studied using additions of various organic solvents at different pH' and ionic strength values. As the optimum emerged systems with 60-70% 1,4-dioxane, pH' 5.3-5.6. After dehydration with sodium hydroxide, dioxane must be freed from the electrode surface-oxidizing impurities by their reduction with sodium metal and subsequent distillation. The method was applied to determination of sulphates in mountain spring waters. Units of ppm can be determined; the limit of determination, however, depends considerably on the content of dioxane, total salt content in the sample, and speed of the semi-automatic titration. Lead can be determined with EDTA in concentrations down to c(Pb2+) = 5 . 10-6 mol l-1.

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Association of benflurone in aqueous solutions studied by measuring the activity of chloride ions

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19862437 ◽

1986 ◽

Vol 51 (11) ◽

pp. 2437-2443

Author(s):

František Kopecký ◽

Mária Vojteková ◽

Milan Pešák

Keyword(s):

Aqueous Solutions ◽

Chloride Ions ◽

Ion Selective Electrode ◽

Selective Electrode ◽

Measured Range

The conventional activity of chloride ions was measured by an ion-selective electrode at 25 °C in aqueous solutions of benflurone, i.e. 5-(2-(N,N-dimethylamino)ethoxy)-7-oxo-7H-benzo(c)fluorene hydrochloride, without or with additions of KCl. These results suggest a gradual association of benflurone; the formation of a hetero-associate, (BH+)2Cl-, followed by higher associates was evaluated in the measured range up to 0.1 mol l-1.

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New method for the study of surface acidity of zeolites by NH3-TPD, using a pH-meter equipped with an ion selective electrode

Catalysis Letters ◽

10.1007/s10562-006-0157-0 ◽

2006 ◽

Vol 112 (1-2) ◽

pp. 13-18 ◽

Cited By ~ 10

Author(s):

R. Le Van Mao ◽

N. Al-Yassir ◽

L. Lu ◽

N. T. Vu ◽

A. Fortier

Keyword(s):

Surface Acidity ◽

New Method ◽

Ion Selective Electrode ◽

Selective Electrode

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Using MoS2/Fe3O4 as Ion-Electron Transduction Layer to Manufacture All-Solid-State Ion-Selective Electrode for Determination of Serum Potassium

Chemosensors ◽

10.3390/chemosensors9070155 ◽

2021 ◽

Vol 9 (7) ◽

pp. 155

Author(s):

Yan Su ◽

Ting Liu ◽

Caiqiao Song ◽

Aiqiao Fan ◽

Nan Zhu ◽

...

Keyword(s):

High Performance ◽

Accurate Determination ◽

Water Layer ◽

Ion Selective Electrode ◽

Potential Response ◽

Selective Electrode ◽

Response Measurement ◽

Long Term Stability

As an essential electrolyte for the human body, the potassium ion (K+) plays many physiological roles in living cells, so the rapid and accurate determination of serum K+ is of great significance. In this work, we developed a solid-contact ion-selective electrode (SC-ISE) using MoS2/Fe3O4 composites as the ion-to-electron transducer to determine serum K+. The potential response measurement of MoS2/Fe3O4/K+-ISE shows a Nernst response by a slope of 55.2 ± 0.1 mV/decade and a low detection limit of 6.3 × 10−6 M. The proposed electrode exhibits outstanding resistance to the interference of O2, CO2, light, and water layer formation. Remarkably, it also presents a high performance in potential reproducibility and long-term stability.

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