Deterpenation of Bergamot Essential Oil Using Liquid−Liquid Extraction: Equilibrium Data of Model Systems at 298.2 K

2011 ◽  
Vol 56 (5) ◽  
pp. 2362-2370 ◽  
Author(s):  
Cristina Chiyoda ◽  
Maria C. Capellini ◽  
Ivana M. Geremias ◽  
Fernanda H. Carvalho ◽  
Keila K. Aracava ◽  
...  
2015 ◽  
Vol 399 ◽  
pp. 87-97 ◽  
Author(s):  
Daniel Gonçalves ◽  
Martin E.E. Teschke ◽  
Cristina C. Koshima ◽  
Cintia B. Gonçalves ◽  
Alessandra L. Oliveira ◽  
...  

2014 ◽  
Vol 69 ◽  
pp. 66-72 ◽  
Author(s):  
Daniel Gonçalves ◽  
Cristina Chiyoda Koshima ◽  
Karina Thiemi Nakamoto ◽  
Thayla Karla Umeda ◽  
Keila Kazue Aracava ◽  
...  

2017 ◽  
Vol 38 (1) ◽  
pp. 97-110 ◽  
Author(s):  
Artur Kubiczek ◽  
Władysław Kamiński

AbstractRoom-temperature ionic liquids (RTILs) are a moderately new class of liquid substances that are characterized by a great variety of possible anion-cation combinations giving each of them different properties. For this reason, they have been termed as designer solvents and, as such, they are particularly promising for liquid-liquid extraction, which has been quite intensely studied over the last decade. This paper concentrates on the recent liquid-liquid extraction studies involving ionic liquids, yet focusing strictly on the separation of n-butanol from model aqueous solutions. Such research is undertaken mainly with the intention of facilitating biological butanol production, which is usually carried out through the ABE fermentation process. So far, various sorts of RTILs have been tested for this purpose while mostly ternary liquid-liquid systems have been investigated. The industrial design of liquid-liquid extraction requires prior knowledge of the state of thermodynamic equilibrium and its relation to the process parameters. Such knowledge can be obtained by performing a series of extraction experiments and employing a certain mathematical model to approximate the equilibrium. There are at least a few models available but this paper concentrates primarily on the NRTL equation, which has proven to be one of the most accurate tools for correlating experimental equilibrium data. Thus, all the presented studies have been selected based on the accepted modeling method. The reader is also shown how the NRTL equation can be used to model liquid-liquid systems containing more than three components as it has been the authors’ recent area of expertise.


2013 ◽  
Vol 15 (3) ◽  
pp. 81-84 ◽  
Author(s):  
Indrasing D. Patil ◽  
Yogita S. Patil ◽  
Bhausaheb L. Pangarkar

Abstract Pesticide pollution is a serious problem being faced. Harmful levels of pesticides are found in the water which is used for daily purposes. In the event of such a scenario, this paper presents a working solution for bringing down the Pesticide levels in the water to safe levels by using the method of liquid-liquid extraction. The experimental liquid-liquid equilibrium data on pesticide-water-solvent ternary mixtures at a temperature of 288.15 K are presented here. The pesticide used here is a chlorinated hydrocarbon called lindane found in the water (underground, land), beverages and foods. The solvents used are Petro-ether-Chloroform (1:1), Ethylene di chloride and n-hexane. The equilibrium generation diagram, triangular diagram, tie lines and bimodal curves as well as the distribution coefficient have been determined and reported. The petro-ether-chloroform was found to be the right solvent for the separation of lindane from wastewater because of high selectivity (25.36) and distribution coefficient (4). The extraction process is simulated into ‘C’ language


2016 ◽  
Vol 163 ◽  
pp. 247-257 ◽  
Author(s):  
Daniel Gonçalves ◽  
Martin Emil Erismann Teschke ◽  
Cristina Chiyoda Koshima ◽  
Christianne Elisabete da Costa Rodrigues

2001 ◽  
Vol 2001 (2) ◽  
pp. 48-49
Author(s):  
Francisco José Alguacil ◽  
Manuel Alonso ◽  
Antonio Cobo

2019 ◽  
Vol 44 (3) ◽  
pp. 43-49
Author(s):  
Aline Amaral Madeira

This article was elaborated in an approach to the liquid-liquid equilibrium of the extraction process of ethanoic acid (C2H4O2) in aqueous phase using ethyl ethanoate as solvent. The liquid-liquid extraction was modeled by the construction of a ternary phase diagram for the water-ethanoic acid- ethyl ethanoate system with the aid of the Origin software. The equilibrium data were obtained experimentally by titration at room temperature (298.15 K) and atmospheric pressure (101325 Pa) using four mixtures of water, ethanoic acid, and ethyl ethanoate. The determination of the composition of the extract and residue portions in the equilibrium of each mixture by of the tie-lines method allowed to examine the percentages of liquid-liquid extraction achieved. The distribution coefficients and separation factors calculated made it possible an evaluation of the distribution and of the mutual solubility of the solute in the aqueous and organic phases. The results showed a good performance of ethyl ethanoate in the extraction of ethanoic acid for concentrations of solute until 16% of the feed.


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