Influence of temperature on the liquid-liquid equilibrium of the ternary system acetonitrile-2-furyloxirane-cyclohexane

1987 ◽  
Vol 32 (3) ◽  
pp. 306-308 ◽  
Author(s):  
Samuel Rakotondramanana ◽  
Marie Elisabeth Borredon ◽  
Jacques Molinier
2018 ◽  
Vol 47 (9) ◽  
pp. 1529-1538
Author(s):  
Jonatán Hernán Veliz ◽  
Alicia Marta Cases ◽  
Constanza Geraldine Varas Gutiérrez ◽  
Mónica Beatriz Gramajo

2011 ◽  
Vol 305 (1) ◽  
pp. 34-38 ◽  
Author(s):  
Mónica B. Gramajo de Doz ◽  
Carlos M. Bonatti ◽  
María C. Lucena ◽  
Diego A. González ◽  
Marcos E. Mancilla

1992 ◽  
Vol 70 (8) ◽  
pp. 2310-2313 ◽  
Author(s):  
Horacio N. Sólimo ◽  
José L. Zurita

To evaluate the influence of temperature on the extraction of ethanol from aqueous solutions with 1,2-dichloroethane, liquid–liquid equilibrium data for the system water + ethanol + 1,2-dichloroethane were obtained at 298.15, 308.15, and 318.15 K. The binodal curves were determined by the cloud-point method, and conjugate points on the tie-lines were obtained by correlating the refractive index of these curves as a function of composition. The tie-line data at each temperature were satisfactorily correlated using the method of Othmer and Tobias, and the plait-point coordinates were estimated. The experimental data were also compared to values calculated by the UNIFAC group contribution method for the activity coefficients using the isoactivity conditions as restraint equations, and with the NRTL and UNIQUAC models. The UNIFAC method proved to be more accurate than the NRTL and UNIQUAC equations fitted to the experimental data. Under the experimental conditions used, ethanol extraction by 1,2-dichloroethane appears to be independent of the temperature.


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