Solubility of carbon dioxide in liquid water and of water in gaseous carbon dioxide in the range 0.2-5 MPa and at temperatures up to 473 K

1981 ◽  
Vol 26 (4) ◽  
pp. 388-391 ◽  
Author(s):  
Andrzej Zawisza ◽  
Boguslawa Malesinska
Keyword(s):  
Carbon Dioxide ◽  
Liquid Water ◽  
Gaseous Carbon Dioxide

Oxygen-18 isotope effects in the liquid water–pyridine system as a probe of intermolecular forces

1977 ◽  
Vol 55 (16) ◽  
pp. 2966-2970 ◽  
Author(s):  
Robert H. Betts ◽  
Jan Bron ◽  
Wayne D. Buchannon ◽  
Kwok-Ying D. Wu
Keyword(s):  
Carbon Dioxide ◽  
Water Molecule ◽  
Mole Fraction ◽  
Liquid Water ◽  
Vapour Pressure ◽  
Isotope Effects ◽  
Pure Water ◽  
Intermolecular Forces ◽  
Average Water ◽  
Gaseous Carbon Dioxide

Oxygen-18 exchange between gaseous carbon dioxide and water in liquid water–pyridine mixtures is used as a probe for changes in intermolecular forces when the composition of the system is changed from pure water to pure pyridine. In agreement with results obtained previously by other methods, it is found that the interaction energy of an 'average' water molecule with the medium decreases when the mole fraction of pyridine is varied from zero to unity. The experimental results are related to the vapour pressure isotope effect, P(H218O)/P(H216O), of the binary mixtures. The utility of the Stern – Van Hook – Wolfsberg equation for vapour pressure isotope effects has been investigated. In addition, a plot of the equilibrium constant of the oxygen-18 exchange reaction vs. the mole fraction of pyridine presents no evidence of the formation of stoichiometric pyridine–water complexes.

The ν1 Band of Carbon Dioxide in Pressure-Induced Absorption. II. Density and Temperature Dependence of the Intensity; Critical Phenomena

1972 ◽  
Vol 50 (12) ◽  
pp. 1355-1362 ◽  
Author(s):  
L. Mannik ◽  
J. C. Stryland
Keyword(s):  
Carbon Dioxide ◽  
Absorption Coefficient ◽  
Density Range ◽  
Induced Absorption ◽  
Lennard Jones ◽  
Molecular Potential ◽  
Band Profile ◽  
Gaseous Carbon Dioxide ◽  
Interaction Term ◽  
Path Lengths

The ν1 band of gaseous carbon dioxide has been studied in pressure-induced absorption at temperatures of ~ 190, ~ 300, and ~ 470 K, over a density range from 0.5 to 300 amagat, and with path lengths from 0.007 to 56 m. The observed temperature variation of the binary absorption coefficient can be satisfactorily accounted for only by adding a quadrupole–quadrupole interaction term to the usual Lennard–Jones model for the inter-molecular potential. The band profile is in agreement with the theory of quadrupole-induced absorption. There is some increase in the intensity of the band near the critical point due to the divergence of the correlation length. A very marked increase in the intensity is possibly prevented by the "cancellation effect".

The role of electrode wettability in electrochemical reduction of carbon dioxide

2021 ◽  
Author(s):  
Mengran Li ◽  
Mohamed Nazmi Idros ◽  
Yuming Wu ◽  
Thomas Burdyny ◽  
Sahil Garg ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Liquid Water ◽  
Substantial Improvement ◽  
Industrial Scale ◽  
High Current ◽  
Current Densities

The electrochemical reduction of carbon dioxide (CO2RR) requires access to ample gaseous CO2 and liquid water to fuel reactions at high current densities for industrial-scale. Substantial improvement of the CO2RR...

Experimental and Numerical Modeling of Gaseous Carbon Dioxide Injecting Into Aqueous Water in Bottle Filler System

2001 ◽  
Author(s):  
Y. H. Zheng ◽  
R. S. Amano
Keyword(s):  
Carbon Dioxide ◽  
Numerical Modeling ◽  
Tap Water ◽  
Co2 Injection ◽  
Operating Characteristics ◽  
Two Phase ◽  
Carbonation Process ◽  
Filling System ◽  
Gas System ◽  
Gaseous Carbon Dioxide

Abstract An efficient enhancement of the carbonation rate in the bottle filling stage can substantially increase the production in beverage industries. The bottle filling system currently used in most of the manufacturers can still be improved for a better performance of carbonation by designing the injection tube system. This paper reports on an experimental and numerical mass transfer modeling that can simulate the dissolution process of gaseous carbon dioxide into aqueous water in the bottle filler system. In order to establish the operating characteristics of the bottle filler system, an ordinary tap water and pure carbon dioxide were used as the liquid-gas system. The two-phase numerical modeling was developed that can serve as a framework for the continuous improvement of the design of the carbonation process in the bottle filler system. For an optimal design of CO2 injection tube and flow conditions, a computational fluid dynamics (CFD) approach is one of the most power tools. However, since only limited experimental data are available in the open literature to verify the computational results, an experiment study was performed to obtain measurements of CO2 level, temperature, and pressure during the carbonation process in the bottle filled with liquid. Both experimental and numerical studies of various flow condition and different sizes of injection tube are presented in this paper.

Effect of high pressure gaseous carbon dioxide on the germination of bacterial spores

2004 ◽  
Vol 91 (2) ◽  
pp. 209-213 ◽  
Author(s):  
S. Furukawa ◽  
T. Watanabe ◽  
T. Tai ◽  
J. Hirata ◽  
N. Narisawa ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
High Pressure ◽  
Bacterial Spores ◽  
Gaseous Carbon Dioxide

Salen ligand complexes as electrocatalysts for direct electrochemical reduction of gaseous carbon dioxide to value added products

RSC Advances ◽  
2015 ◽  
Vol 5 (5) ◽  
pp. 3581-3589 ◽  
Author(s):  
Surya Singh ◽  
Bedika Phukan ◽  
Chandan Mukherjee ◽  
Anil Verma
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Value Added ◽  
Salen Complexes ◽  
Gaseous Carbon Dioxide ◽  
Salen Ligand ◽  
Centrosymmetric Molecule ◽  
Value Added Products

CO2, being a linear and centrosymmetric molecule, is very stable, and the electrochemical reduction of CO2 requires energy. However, the salen complexes are found to be very efficient to minimize overpotential as compared to their metal counterparts.

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