The ν1 Band of Carbon Dioxide in Pressure-Induced Absorption. II. Density and Temperature Dependence of the Intensity; Critical Phenomena

1972 ◽  
Vol 50 (12) ◽  
pp. 1355-1362 ◽  
Author(s):  
L. Mannik ◽  
J. C. Stryland
Keyword(s):  
Carbon Dioxide ◽  
Absorption Coefficient ◽  
Density Range ◽  
Induced Absorption ◽  
Lennard Jones ◽  
Molecular Potential ◽  
Band Profile ◽  
Gaseous Carbon Dioxide ◽  
Interaction Term ◽  
Path Lengths

The ν1 band of gaseous carbon dioxide has been studied in pressure-induced absorption at temperatures of ~ 190, ~ 300, and ~ 470 K, over a density range from 0.5 to 300 amagat, and with path lengths from 0.007 to 56 m. The observed temperature variation of the binary absorption coefficient can be satisfactorily accounted for only by adding a quadrupole–quadrupole interaction term to the usual Lennard–Jones model for the inter-molecular potential. The band profile is in agreement with the theory of quadrupole-induced absorption. There is some increase in the intensity of the band near the critical point due to the divergence of the correlation length. A very marked increase in the intensity is possibly prevented by the "cancellation effect".

Experimental and Numerical Modeling of Gaseous Carbon Dioxide Injecting Into Aqueous Water in Bottle Filler System

2001 ◽  
Author(s):  
Y. H. Zheng ◽  
R. S. Amano
Keyword(s):  
Carbon Dioxide ◽  
Numerical Modeling ◽  
Tap Water ◽  
Co2 Injection ◽  
Operating Characteristics ◽  
Two Phase ◽  
Carbonation Process ◽  
Filling System ◽  
Gas System ◽  
Gaseous Carbon Dioxide

Abstract An efficient enhancement of the carbonation rate in the bottle filling stage can substantially increase the production in beverage industries. The bottle filling system currently used in most of the manufacturers can still be improved for a better performance of carbonation by designing the injection tube system. This paper reports on an experimental and numerical mass transfer modeling that can simulate the dissolution process of gaseous carbon dioxide into aqueous water in the bottle filler system. In order to establish the operating characteristics of the bottle filler system, an ordinary tap water and pure carbon dioxide were used as the liquid-gas system. The two-phase numerical modeling was developed that can serve as a framework for the continuous improvement of the design of the carbonation process in the bottle filler system. For an optimal design of CO2 injection tube and flow conditions, a computational fluid dynamics (CFD) approach is one of the most power tools. However, since only limited experimental data are available in the open literature to verify the computational results, an experiment study was performed to obtain measurements of CO2 level, temperature, and pressure during the carbonation process in the bottle filled with liquid. Both experimental and numerical studies of various flow condition and different sizes of injection tube are presented in this paper.

scholarly journals Absorption coefficient of carbon dioxide across atmospheric troposphere layer

Heliyon ◽  
2018 ◽  
Vol 4 (10) ◽  
pp. e00785 ◽  
Author(s):  
Peng-Sheng Wei ◽  
Yin-Chih Hsieh ◽  
Hsuan-Han Chiu ◽  
Da-Lun Yen ◽  
Chieh Lee ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Absorption Coefficient

Light-induced absorption and optical damage in Sc-, Mg-, and Zn-doped near-stoichiometric LiNbO3

2018 ◽  
Vol 27 (03) ◽  
pp. 1850030 ◽  
Author(s):  
Junsheng Li ◽  
Youwen Liu ◽  
Huijie Zhang ◽  
Liangzun Tang ◽  
Chongjun He
Keyword(s):  
Steady State ◽  
Lithium Niobate ◽  
Absorption Coefficient ◽  
Ultraviolet Light ◽  
Infrared Absorption ◽  
Doping Level ◽  
Doping Concentration ◽  
Weak Absorption ◽  
Induced Absorption ◽  
Infrared Absorption Spectra

By measuring the ultraviolet-light-induced absorption in Sc-, Mg- and Zn-doped near-stoichiometric lithium niobate (LiNbO[Formula: see text], we find that the steady-state ultraviolet-light-induced absorption coefficient changes with respect to the doping concentration. There is a strong ultraviolet-light-induced absorption when doping concentration is below its photorefractive threshold and a really weak absorption when the crystal is highly doped. We also use OH[Formula: see text] infrared absorption spectra and the transmitted light spot distortion method to verify the result. Thus, we can determine if the doping level in these doped near-stoichiometric LiNbO3 crystals is above or below their photorefractive threshold by measuring the ultraviolet-light-induced absorption.

Effect of high pressure gaseous carbon dioxide on the germination of bacterial spores

2004 ◽  
Vol 91 (2) ◽  
pp. 209-213 ◽  
Author(s):  
S. Furukawa ◽  
T. Watanabe ◽  
T. Tai ◽  
J. Hirata ◽  
N. Narisawa ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
High Pressure ◽  
Bacterial Spores ◽  
Gaseous Carbon Dioxide

Salen ligand complexes as electrocatalysts for direct electrochemical reduction of gaseous carbon dioxide to value added products

RSC Advances ◽  
2015 ◽  
Vol 5 (5) ◽  
pp. 3581-3589 ◽  
Author(s):  
Surya Singh ◽  
Bedika Phukan ◽  
Chandan Mukherjee ◽  
Anil Verma
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Value Added ◽  
Salen Complexes ◽  
Gaseous Carbon Dioxide ◽  
Salen Ligand ◽  
Centrosymmetric Molecule ◽  
Value Added Products

CO2, being a linear and centrosymmetric molecule, is very stable, and the electrochemical reduction of CO2 requires energy. However, the salen complexes are found to be very efficient to minimize overpotential as compared to their metal counterparts.

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