Excess Volumes and Speed of Sound of Ternary Mixtures of 2-Methoxyethanol (1) + Butyl Acetate (2) + Aromatic Hydrocarbons (3) at 303.15 K

1995 ◽  
Vol 40 (1) ◽  
pp. 128-131 ◽  
Author(s):  
Kalahasti M. Krishnan ◽  
Kantipudi Rambabu ◽  
Ponneri Venkateswarlu ◽  
Gorijala K. Raman
Keyword(s):  
Aromatic Hydrocarbons ◽  
Speed Of Sound ◽  
Butyl Acetate ◽  
Excess Volumes ◽  
Ternary Mixtures

A thermodynamic study on binary and ternary mixtures of acetonitrile, water and butyl acetate

2002 ◽  
Vol 203 (1-2) ◽  
pp. 83-98 ◽  
Author(s):  
Jhoany Acosta ◽  
Alberto Arce ◽  
Eva Rodil ◽  
Ana Soto
Keyword(s):  
Butyl Acetate ◽  
Thermodynamic Study ◽  
Ternary Mixtures ◽  
Binary And Ternary Mixtures

Speed of Sound and Viscosities of Butyl Acetate and Substituted Alcohols at 303.15 K

1996 ◽  
Vol 33 (1) ◽  
pp. 1-16 ◽  
Author(s):  
D. Ramachandran ◽  
K. Rambabu ◽  
P. Venkateswarlu ◽  
K. Mohankrishnan ◽  
G. K. Raman
Keyword(s):  
Speed Of Sound ◽  
Butyl Acetate

scholarly journals Unusually sluggish microemulsion system with water, toluene and a technical branched alkyl polyethoxylate

2015 ◽  
Vol 21 (3) ◽  
pp. 429-439 ◽  
Author(s):  
Marija Ilic ◽  
Franz-Hubert Haegel ◽  
Vesna Pavelkic ◽  
Snezana Zlatanovic ◽  
Zoran Markovic ◽  
...  
Keyword(s):  
Aromatic Hydrocarbons ◽  
Nonionic Surfactants ◽  
Binary Phase Diagram ◽  
Visual Observation ◽  
Ternary Mixtures ◽  
Microemulsion System ◽  
Slow Kinetics ◽  
Bicontinuous Microemulsion ◽  
Kinetics Of ◽  
Qualitative Measurements

Microemulsion systems with water, toluene and nonionic surfactants are interesting for application due to the excellent solvent properties of aromatic hydrocarbons. In this study, the pseudo-binary phase diagram (?fish-diagram?) of such a ternary system was investigated using a branched technical alkyl polyethoxylate. Lutensol ON 50 (i-C10E5) was considered a suitable surfactant. The system with technical branched i-C10E5 exhibits very long and for compositions near optimum solubilization, i.e. the minimum content of surfactant needed for a bicontinuous microemulsion, extremely long times for equilibration. In addition to visual observation, qualitative measurements of turbidity were performed with a UV-Vis spectrometer for characterizing the behavior of this unusually sluggish system. Isothermal phase diagrams at 20, 25 and 30?C yielded inconsistent results after the change of temperature and the application of mechanical stress for different treatment of the samples. Ternary mixtures of water, toluene, and Lutensol ON 50 seem to form long-living metastable states. The sluggishness and the ambiguous phase behavior of the system are discussed. Inconsistent results are attributed to the slow kinetics of the formation and destruction of liquid crystals and the ability of the system to form miniemulsions within an unusual concentration range.

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