Palladium-Catalyzed Homocoupling of Highly Fluorinated Arylboronates: Studies of the Influence of Strongly vs Weakly Coordinating Solvents on the Reductive Elimination Process

2020 ◽  
Vol 142 (13) ◽  
pp. 6036-6050 ◽  
Author(s):  
Yudha P. Budiman ◽  
Arumugam Jayaraman ◽  
Alexandra Friedrich ◽  
Florian Kerner ◽  
Udo Radius ◽  
...  
Keyword(s):  
Reductive Elimination ◽  
Elimination Process ◽  
Palladium Catalyzed ◽  
Weakly Coordinating

Computational Study of the Palladium-Catalyzed Carbonylative Synthesis of Aromatic Acid Chlorides: The Synergistic Effect of Pt Bu3 and CO on Reductive Elimination

2016 ◽  
Vol 22 (42) ◽  
pp. 15107-15118 ◽  
Author(s):  
Jeffrey S. Quesnel ◽  
Salvador Moncho ◽  
Kai E. O. Ylijoki ◽  
Gerardo Martin Torres ◽  
Edward N. Brothers ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Computational Study ◽  
Reductive Elimination ◽  
Aromatic Acid ◽  
Acid Chlorides ◽  
Palladium Catalyzed

Mechanochemical palladium-catalyzed C(sp2)–H homocoupling of N-arylcarbamates: synthesis of 2,2′-biaryldiamines

2018 ◽  
Vol 5 (13) ◽  
pp. 2103-2107 ◽  
Author(s):  
Yiyi Weng ◽  
Tianwen Lan ◽  
Chen Sun ◽  
Ting Yang ◽  
Weike Su ◽  
...  
Keyword(s):  
Ball Milling ◽  
High Speed ◽  
Palladium Catalyzed ◽  
Weakly Coordinating ◽  
High Speed Ball Milling

The palladium-catalyzed dehydrogenative C(sp2)–H homocoupling of N-arylcarbamates under high-speed ball-milling conditions has been achieved using weakly coordinating directing groups, providing access to a variety of 2,2′-biaryldicarbamates.

scholarly journals Palladium-catalyzed regio- and stereoselective synthesis of aryl and 3-indolyl-substituted 4-methylene-3,4-dihydroisoquinolin-1(2H)-ones

2020 ◽  
Vol 16 ◽  
pp. 1084-1091 ◽  
Author(s):  
Valeria Nori ◽  
Antonio Arcadi ◽  
Armando Carlone ◽  
Fabio Marinelli ◽  
Marco Chiarini
Keyword(s):  
Stereoselective Synthesis ◽  
Reductive Elimination ◽  
Aryl Iodide ◽  
Arylboronic Acids ◽  
Palladium Catalyzed

Cascade cyclocarbopalladation of the readily available aryl/alkyl-substituted propargylic amides containing an aryl iodide moiety, followed by Suzuki–Miyaura coupling with arylboronic acids, allowed an efficient regio- and stereoselective synthesis of tetrasubstituted 4-methylene-3,4-dihydroisoquinolin-1(2H)-ones. Moreover, cascade cyclocarbopalladation, followed by the reaction with 2-alkynyltrifluoroacetanilides, accomplished a double cyclization to afford challenging 4-methylene-3,4-dihydroisoquinolin-1(2H)-ones bearing a 3-indolyl substituent through aminopalladation/reductive elimination.

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