scholarly journals Pyridine-Based PCP-Ruthenium Complexes: Unusual Structures and Metal–Ligand Cooperation

2019 ◽  
Vol 141 (18) ◽  
pp. 7554-7561 ◽  
Author(s):  
Shan Tang ◽  
Niklas von Wolff ◽  
Yael Diskin-Posner ◽  
Gregory Leitus ◽  
Yehoshoa Ben-David ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Metal Ligand

Ruthenium complexes bearing an unsymmetrical pincer ligand with a 2-hydroxypyridylmethylene fragment: active catalysts for transfer hydrogenation of ketones

2016 ◽  
Vol 45 (11) ◽  
pp. 4828-4834 ◽  
Author(s):  
Jing Shi ◽  
Bowen Hu ◽  
Dawei Gong ◽  
Shu Shang ◽  
Guangfeng Hou ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Pincer Ligand ◽  
Hydrogenation Activity ◽  
Catalytic Transfer ◽  
Metal Ligand

The synthesis, reactivity and catalytic transfer hydrogenation activity of three metal–ligand cooperative ruthenium(ii) complexes (3–5) with a 2-hydroxypyridylmethylene fragment are reported.

Stepwise Metal-Ligand Cooperation by a Reversible Aromatization/Deconjugation Sequence in Ruthenium Complexes with a Tetradentate Phenanthroline-Based Ligand

2013 ◽  
Vol 19 (10) ◽  
pp. 3407-3414 ◽  
Author(s):  
Robert Langer ◽  
Ido Fuchs ◽  
Matthias Vogt ◽  
Ekambaram Balaraman ◽  
Yael Diskin-Posner ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Metal Ligand

Enantioselective Guest Binding and Dynamic Resolution of Cationic Ruthenium Complexes by a Chiral Metal−Ligand Assembly

2004 ◽  
Vol 126 (12) ◽  
pp. 3674-3675 ◽  
Author(s):  
Dorothea Fiedler ◽  
Dennis H. Leung ◽  
Robert G. Bergman ◽  
Kenneth N. Raymond
Keyword(s):  
Ruthenium Complexes ◽  
Guest Binding ◽  
Dynamic Resolution ◽  
Metal Ligand

Role of coherent nuclear motion in the ultrafast intersystem crossing of ruthenium complexes

2020 ◽  
Vol 22 (44) ◽  
pp. 25811-25818
Author(s):  
JunWoo Kim ◽  
Dong-gu Kang ◽  
Sang Kyu Kim ◽  
Taiha Joo
Keyword(s):  
Symmetry Breaking ◽  
Wave Packets ◽  
Ruthenium Complexes ◽  
Nuclear Motion ◽  
Intersystem Crossing ◽  
Vibrational Modes ◽  
Time Resolved ◽  
Strongly Coupled ◽  
Metal Ligand

Ultrafast intersystem crossing (ISC) of ruthenium complexes is time-resolved directly. Coherent nuclear wave packets suggest that metal–ligand stretching or symmetry breaking vibrational modes are strongly coupled with the ISC.

Metal–ligand cooperative C–O bond cleavage of propargylic alcohol with protic pyrazole complexes of ruthenium

2019 ◽  
Vol 220 ◽  
pp. 364-375
Author(s):  
Naoto Tashima ◽  
Satomi Ohta ◽  
Shigeki Kuwata
Keyword(s):  
Bond Cleavage ◽  
Ruthenium Complexes ◽  
Propargylic Alcohol ◽  
Metal Ligand

Protic pyrazole–ruthenium complexes promoted the C–O and C–H bond cleavage of a propargylic alcohol through metal–ligand cooperation.

Sign in / Sign up

Export Citation Format

Share Document