Enantioselective Guest Binding and Dynamic Resolution of Cationic Ruthenium Complexes by a Chiral Metal−Ligand Assembly

2004 ◽  
Vol 126 (12) ◽  
pp. 3674-3675 ◽  
Author(s):  
Dorothea Fiedler ◽  
Dennis H. Leung ◽  
Robert G. Bergman ◽  
Kenneth N. Raymond
Keyword(s):  
Ruthenium Complexes ◽  
Guest Binding ◽  
Dynamic Resolution ◽  
Metal Ligand

Zwitterionic Ru(III) Complexes: Stability of Metal–Ligand Bond and Host–Guest Binding with Cucurbit[7]uril

2020 ◽  
Vol 59 (14) ◽  
pp. 10185-10196
Author(s):  
Sanaz Malali ◽  
Jan Chyba ◽  
Michal Knor ◽  
Michal Horní ◽  
Marek Nečas ◽  
...  
Keyword(s):  
Guest Binding ◽  
Metal Ligand ◽  
Ligand Bond

Ruthenium complexes bearing an unsymmetrical pincer ligand with a 2-hydroxypyridylmethylene fragment: active catalysts for transfer hydrogenation of ketones

2016 ◽  
Vol 45 (11) ◽  
pp. 4828-4834 ◽  
Author(s):  
Jing Shi ◽  
Bowen Hu ◽  
Dawei Gong ◽  
Shu Shang ◽  
Guangfeng Hou ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Pincer Ligand ◽  
Hydrogenation Activity ◽  
Catalytic Transfer ◽  
Metal Ligand

The synthesis, reactivity and catalytic transfer hydrogenation activity of three metal–ligand cooperative ruthenium(ii) complexes (3–5) with a 2-hydroxypyridylmethylene fragment are reported.

scholarly journals Pyridine-Based PCP-Ruthenium Complexes: Unusual Structures and Metal–Ligand Cooperation

2019 ◽  
Vol 141 (18) ◽  
pp. 7554-7561 ◽  
Author(s):  
Shan Tang ◽  
Niklas von Wolff ◽  
Yael Diskin-Posner ◽  
Gregory Leitus ◽  
Yehoshoa Ben-David ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Metal Ligand

Stepwise Metal-Ligand Cooperation by a Reversible Aromatization/Deconjugation Sequence in Ruthenium Complexes with a Tetradentate Phenanthroline-Based Ligand

2013 ◽  
Vol 19 (10) ◽  
pp. 3407-3414 ◽  
Author(s):  
Robert Langer ◽  
Ido Fuchs ◽  
Matthias Vogt ◽  
Ekambaram Balaraman ◽  
Yael Diskin-Posner ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Metal Ligand

Role of coherent nuclear motion in the ultrafast intersystem crossing of ruthenium complexes

2020 ◽  
Vol 22 (44) ◽  
pp. 25811-25818
Author(s):  
JunWoo Kim ◽  
Dong-gu Kang ◽  
Sang Kyu Kim ◽  
Taiha Joo
Keyword(s):  
Symmetry Breaking ◽  
Wave Packets ◽  
Ruthenium Complexes ◽  
Nuclear Motion ◽  
Intersystem Crossing ◽  
Vibrational Modes ◽  
Time Resolved ◽  
Strongly Coupled ◽  
Metal Ligand

Ultrafast intersystem crossing (ISC) of ruthenium complexes is time-resolved directly. Coherent nuclear wave packets suggest that metal–ligand stretching or symmetry breaking vibrational modes are strongly coupled with the ISC.

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