Directed Decarbonylation of Unstrained Aryl Ketones via Nickel-Catalyzed C—C Bond Cleavage

2018 ◽  
Vol 140 (2) ◽  
pp. 586-589 ◽  
Author(s):  
Tian-Tian Zhao ◽  
Wen-Hua Xu ◽  
Zhao-Jing Zheng ◽  
Peng-Fei Xu ◽  
Hao Wei
Keyword(s):  
Bond Cleavage ◽  
Aryl Ketones

ChemInform Abstract: Extrusion of CO from Aryl Ketones: Rhodium(I)-Catalyzed C-C Bond Cleavage Directed by a Pyridine Group.

ChemInform ◽  
2012 ◽  
Vol 43 (29) ◽  
pp. no-no
Author(s):  
Zhi-Quan Lei ◽  
Hu Li ◽  
Yang Li ◽  
Xi-Sha Zhang ◽  
Kang Chen ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Pyridine Group ◽  
Aryl Ketones

Chemoselective Synthesis of Aryl Ketones from Amides and Grignard Reagents via C(O)–N Bond Cleavage under Catalyst-Free Conditions

2019 ◽  
Vol 84 (18) ◽  
pp. 11823-11838 ◽  
Author(s):  
Popuri Sureshbabu ◽  
Sadaf Azeez ◽  
Nalluchamy Muniyappan ◽  
Shahulhameed Sabiah ◽  
Jeyakumar Kandasamy
Keyword(s):  
Bond Cleavage ◽  
Grignard Reagents ◽  
Catalyst Free ◽  
Chemoselective Synthesis ◽  
Aryl Ketones

Extrusion of CO from Aryl Ketones: Rhodium(I)-Catalyzed CC Bond Cleavage Directed by a Pyridine Group

2012 ◽  
Vol 51 (11) ◽  
pp. 2690-2694 ◽  
Author(s):  
Zhi-Quan Lei ◽  
Hu Li ◽  
Yang Li ◽  
Xi-Sha Zhang ◽  
Kang Chen ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Pyridine Group ◽  
Aryl Ketones

Iodine-catalyzed oxidative C–C bond cleavage for benzoic acids and benzamides from alkyl aryl ketones

RSC Advances ◽  
2016 ◽  
Vol 6 (27) ◽  
pp. 22749-22753 ◽  
Author(s):  
Pochampalli Sathyanarayana ◽  
Atul Upare ◽  
Owk Ravi ◽  
Prathap Reddy Muktapuram ◽  
Surendar Reddy Bathula
Keyword(s):  
Bond Cleavage ◽  
Benzoic Acids ◽  
Aromatic Acids ◽  
Cleavage Reaction ◽  
Alkyl Aryl ◽  
Bond Cleavage Reaction ◽  
Aryl Ketones

Iodine-catalyzed, aerial oxygen supported C–C bond cleavage reaction of aryl alkyl ketones for the synthesis of benzoic acids and benzamides. Also benzylidene acetones and phenylacetylenes were converted to their aromatic acids at this conditions.

Cationic iridium–BINAP complex-catalyzed addition of aryl ketones to alkynes and alkenes via directed C–H bond cleavage

2008 ◽  
Vol 693 (26) ◽  
pp. 3939-3942 ◽  
Author(s):  
Kyoji Tsuchikama ◽  
Mitsugu Kasagawa ◽  
Yu-Ki Hashimoto ◽  
Kohei Endo ◽  
Takanori Shibata
Keyword(s):  
Bond Cleavage ◽  
Aryl Ketones

ChemInform Abstract: Iodine-Catalyzed Oxidative C-C Bond Cleavage for Benzoic Acids and Benzamides from Alkyl Aryl Ketones.

ChemInform ◽  
2016 ◽  
Vol 47 (28) ◽  
Author(s):  
Pochampalli Sathyanarayana ◽  
Atul Upare ◽  
Owk Ravi ◽  
Prathap Reddy Muktapuram ◽  
Surendar Reddy Bathula
Keyword(s):  
Bond Cleavage ◽  
Benzoic Acids ◽  
Alkyl Aryl ◽  
Aryl Ketones

Extrusion of CO from Aryl Ketones: Rhodium(I)-Catalyzed CC Bond Cleavage Directed by a Pyridine Group

2012 ◽  
Vol 124 (11) ◽  
pp. 2744-2748 ◽  
Author(s):  
Zhi-Quan Lei ◽  
Hu Li ◽  
Yang Li ◽  
Xi-Sha Zhang ◽  
Kang Chen ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Pyridine Group ◽  
Aryl Ketones

Water Phase, Room Temperature, Ligand-Free Suzuki-Miyaura Cross-Coupling: A Green Gateway to Aryl Ketones by C-N Bond Cleavage

2020 ◽  
Vol 2020 (11) ◽  
pp. 1620-1628 ◽  
Author(s):  
Yuqi Zhang ◽  
Zijia Wang ◽  
Zhao Tang ◽  
Zhongfeng Luo ◽  
Hongxiang Wu ◽  
...  
Keyword(s):  
Room Temperature ◽  
Bond Cleavage ◽  
Cross Coupling ◽  
Water Phase ◽  
Ligand Free ◽  
Aryl Ketones

Cu-catalyzed aerobic oxidative amidation of aryl alkyl ketones with azoles to afford tertiary amides via selective C–C bond cleavage

2015 ◽  
Vol 2 (7) ◽  
pp. 765-770 ◽  
Author(s):  
Wen Ding ◽  
Qiuling Song
Keyword(s):  
Molecular Oxygen ◽  
Bond Cleavage ◽  
Alkyl Groups ◽  
Aryl Ketones ◽  
Oxidative Amidation ◽  
Tertiary Amides ◽  
Long Chain

Chemoselective cleavage of the C(CO)–C(alkyl) bond in aryl ketones leading to azole amides is disclosed. Aryl ketones with a variety of long-chain alkyl groups have been demonstrated to be active substrates and mechanism studies suggested that molecular oxygen serves both as an oxidant and a reactant in this strategy.

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