Bottom-Up Solid-State Molecular Assembly via Guest-Induced Intermolecular Interactions

2021 ◽  
Author(s):  
Jia-Rui Wu ◽  
Zhi Cai ◽  
Gengxin Wu ◽  
Dihua Dai ◽  
Yu-Qing Liu ◽  
...  
Keyword(s):  
Solid State ◽  
Intermolecular Interactions ◽  
Molecular Assembly ◽  
Bottom Up

scholarly journals Supramolecular interactions in the solid state

IUCrJ ◽  
2015 ◽  
Vol 2 (6) ◽  
pp. 675-690 ◽  
Author(s):  
Giuseppe Resnati ◽  
Elena Boldyreva ◽  
Petra Bombicz ◽  
Masaki Kawano
Keyword(s):  
Solid State ◽  
Intermolecular Interactions ◽  
Historical Review ◽  
Covalent Bond ◽  
Halogen Bonding ◽  
Molecular Assembly ◽  
Supramolecular Interactions ◽  
Ambient Conditions ◽  
Chemical Research ◽  
Primary Means

In the last few decades, supramolecular chemistry has been at the forefront of chemical research, with the aim of understanding chemistry beyond the covalent bond. Since the long-range periodicity in crystals is a product of the directionally specific short-range intermolecular interactions that are responsible for molecular assembly, analysis of crystalline solids provides a primary means to investigate intermolecular interactions and recognition phenomena. This article discusses some areas of contemporary research involving supramolecular interactions in the solid state. The topics covered are: (1) an overview and historical review of halogen bonding; (2) exploring non-ambient conditions to investigate intermolecular interactions in crystals; (3) the role of intermolecular interactions in morphotropy, being the link between isostructurality and polymorphism; (4) strategic realisation of kinetic coordination polymers by exploiting multi-interactive linker molecules. The discussion touches upon many of the prerequisites for controlled preparation and characterization of crystalline materials.

scholarly journals Convenient Access to Functionalized Non-Symmetrical Atropisomeric 4,4′-Bipyridines

Compounds ◽  
2021 ◽  
Vol 1 (2) ◽  
pp. 58-74
Author(s):  
Emmanuel Aubert ◽  
Emmanuel Wenger ◽  
Paola Peluso ◽  
Victor Mamane
Keyword(s):  
Solid State ◽  
Intermolecular Interactions ◽  
Medicinal Chemistry ◽  
Crystal Packing ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Halogen Bonds ◽  
Cross Coupling Reactions ◽  
Cyano Groups ◽  
Post Functionalization

Non-symmetrical chiral 4,4′-bipyridines have recently found interest in organocatalysis and medicinal chemistry. In this regard, the development of efficient methods for their synthesis is highly desirable. Herein, a series of non-symmetrical atropisomeric polyhalogenated 4,4′-bipyridines were prepared and further functionalized by using cross-coupling reactions. The desymmetrization step is based on the N-oxidation of one of the two pyridine rings of the 4,4′-bipyridine skeleton. The main advantage of this methodology is the possible post-functionalization of the pyridine N-oxide, allowing selective introduction of chlorine, bromine or cyano groups in 2- and 2′-postions of the chiral atropisomeric 4,4′-bipyridines. The crystal packing in the solid state of some newly prepared derivatives was analyzed and revealed the importance of halogen bonds in intermolecular interactions.

Substituent and Solvent Effects on Intermolecular Interactions in Crystals of N-Acylhydrazone Derivatives: Single-Crystal X-ray, Solid-State NMR, and Computational Studies

2014 ◽  
Vol 14 (5) ◽  
pp. 2263-2281 ◽  
Author(s):  
Liliana Mazur ◽  
Katarzyna N. Jarzembska ◽  
Radosław Kamiński ◽  
Krzysztof Woźniak ◽  
Edyta Pindelska ◽  
...  
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Intermolecular Interactions ◽  
Solvent Effects ◽  
Solid State Nmr ◽  
Computational Studies ◽  
X Ray

Minute Torsional Reorganization Elicited Large Visible Range Fluorescence Gain in Terphenyl Derived Crystals

2022 ◽  
Author(s):  
Tapan Ghosh ◽  
Madalasa Mondal ◽  
Ratheesh Vijayaraghavan
Keyword(s):  
Solid State ◽  
Intermolecular Interactions ◽  
Organic Semiconductor ◽  
Structural Rearrangement ◽  
Semiconductor Materials ◽  
Visible Range ◽  
Optical Signals ◽  
Electro Optic ◽  
Organic Semiconductor Materials

Understanding the variations in the solid-state optical signals of organic semiconductor materials upon subtle structural rearrangement or intermolecular interactions would help to extract the best performance in their electro-optic devices....

scholarly journals Solid-State NMR Identification of Intermolecular Interactions in Amelogenin Bound to Hydroxyapatite

2018 ◽  
Vol 115 (9) ◽  
pp. 1666-1672 ◽  
Author(s):  
Rajith Jayasinha Arachchige ◽  
Sarah D. Burton ◽  
Jun-Xia Lu ◽  
Bojana Ginovska ◽  
Larisa K. Harding ◽  
...  
Keyword(s):  
Solid State ◽  
Intermolecular Interactions ◽  
Solid State Nmr ◽  
Nmr Identification
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