Carbon Monoxide Coupling Reactions via a Frustrated Lewis Pair-Derived η2-Formyl Borane

2021 ◽  
Vol 143 (37) ◽  
pp. 14992-14997
Author(s):  
Qiu Sun ◽  
Constantin G. Daniliuc ◽  
Klaus Bergander ◽  
Gerald Kehr ◽  
Gerhard Erker
Keyword(s):  
Carbon Monoxide ◽  
Coupling Reactions ◽  
Frustrated Lewis Pair

Carbon Monoxide Bond Cleavage Mediated by an Intramolecular Frustrated Lewis Pair: Access to New B/N Heterocycles via Selective Incorporation of Single Carbon Atoms

2021 ◽  
Author(s):  
Clemens Krempner ◽  
Chamila Manankandayalage ◽  
Daniel K Unruh
Keyword(s):  
Carbon Monoxide ◽  
Bond Cleavage ◽  
Frustrated Lewis Pair ◽  
Selective Incorporation

Utilizing an intramolecular frustrated Lewis pair (FLP) decorated with a strongly donating guanidino moiety enabled the formation of a thermally remarkably stable FLP-CO adduct, which at 120°C underwent CO migration...

Using the Secondary PH/BH Functional Groups of an Active Geminal Frustrated Lewis Pair for Carbon Monoxide Reduction and Reactions with Nitriles and Isonitriles

2020 ◽  
Vol 132 (30) ◽  
pp. 12577-12583
Author(s):  
Jun Li ◽  
Christian Mück‐Lichtenfeld ◽  
Constantin G. Daniliuc ◽  
Gerald Kehr ◽  
Gerhard Erker
Keyword(s):  
Carbon Monoxide ◽  
Functional Groups ◽  
Frustrated Lewis Pair ◽  
Carbon Monoxide Reduction

Carbonylative Suzuki coupling reactions catalyzed by ONO pincer–type Pd(II) complexes using chloroform as a carbon monoxide surrogate

2020 ◽  
Vol 34 (3) ◽  
Author(s):  
Samaresh Layek ◽  
Bhumika Agrahari ◽  
Rakesh Ganguly ◽  
Parthasarathi Das ◽  
Devendra D. Pathak
Keyword(s):  
Carbon Monoxide ◽  
Suzuki Coupling ◽  
Coupling Reactions

Coupling of Carbon Monoxide with Nitrogen Monoxide at a Frustrated Lewis Pair Template

2016 ◽  
Vol 128 (32) ◽  
pp. 9362-9365 ◽  
Author(s):  
Ke‐Yin Ye ◽  
Gerald Kehr ◽  
Constantin G. Daniliuc ◽  
Lei Liu ◽  
Stefan Grimme ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Nitrogen Monoxide ◽  
Frustrated Lewis Pair

Ruthenium- and Rhodium-Catalyzed Ring-Opening Coupling Reactions of Cyclopropenones with Alkenes or Alkynes

Synlett ◽  
2018 ◽  
Vol 29 (06) ◽  
pp. 717-722 ◽  
Author(s):  
Teruyuki Kondo ◽  
Ryosuke Taniguchi ◽  
Yu Kimura
Keyword(s):  
Carbon Monoxide ◽  
Catalytic Activity ◽  
Methyl Acrylate ◽  
Ring Opening ◽  
Argon Atmosphere ◽  
High Catalytic Activity ◽  
Rhodium Complexes ◽  
Coupling Reactions ◽  
Internal Alkynes ◽  
High Yields

Ru3(CO)12-catalyzed divergent ring-opening coupling reactions of a cyclopropenone with methyl acrylate (an electron-deficient alkene) are developed. Under an argon atmosphere, a decarbonylative linear codimer is obtained, while cyclopentenones are obtained under carbon monoxide (20 atm) without decarbonylation. While ruthenium complexes show no catalytic activity for the ring-opening cocyclization of cyclopropenones with ethylene (20 atm) or bicyclo[2.2.1]hept-2-ene (2-norbornene), rhodium complexes, especially [RhCl(η4-1,5-cod)]2, show high catalytic activity for the desired cocyclization reactions to give the corresponding cyclopentenones in high yields and selectivities. In addition, [RhCl(η4-1,5-cod)]2 realizes the catalytic ring-opening co­cyclization of cyclopropenones with internal alkynes to give the corresponding cyclopentadienones. In all these reactions, ruthena- or rhodacyclobutenones are considered to be key intermediates, generated by strain-driven oxidative addition of a cyclopropenone C–C bond to an ­active ruthenium or rhodium species.

Gold Nanoparticles as Efficient Catalysts in Organic Transformations

2021 ◽  
Vol 22 ◽  
Author(s):  
Irshad A. Wani ◽  
Sapan K. Jain ◽  
Huma Khan ◽  
Abul Kalam ◽  
Tokeer Ahmad
Keyword(s):  
Carbon Monoxide ◽  
Gold Nanoparticles ◽  
Fuel Cells ◽  
Liquid Phase ◽  
Industrial Applications ◽  
Coupling Reactions ◽  
Chemical Transformations ◽  
Organic Transformations ◽  
Catalytic Materials

Abstract: This review summarizes the utilization of gold nanoparticles as efficient catalysts for a variety of chemical transformations like oxidation, hydrogenation and coupling reactions as compared to the conventional catalytic materials. This review explores the gold nanoparticles based catalysts for the liquid phase chemo-selective organic transformations which are proving to be evergreen reactions and has importance for industrial applications. Apart from organic transformation reactions gold nanoparticles has been found to be applicable in removing the atmospheric contaminants and improving the efficiency of the fuel cells by removing the impurities of carbon monoxide.

scholarly journals Radical carbonylations using a continuous microflow system

2009 ◽  
Vol 5 ◽  
Author(s):  
Takahide Fukuyama ◽  
Md Taifur Rahman ◽  
Naoya Kamata ◽  
Ilhyong Ryu
Keyword(s):  
Carbon Monoxide ◽  
Alkyl Halides ◽  
Coupling Reactions ◽  
Tributyltin Hydride ◽  
Microflow Reactor ◽  
Three Component Coupling

Radical-based carbonylation reactions of alkyl halides were conducted in a microflow reactor under pressurized carbon monoxide gas. Good to excellent yields of carbonylated products were obtained via radical formylation, carbonylative cyclization and three-component coupling reactions, using tributyltin hydride or TTMSS as a radical mediator.

scholarly journals Colorimetric metal‐free detection of carbon monoxide: reversible CO uptake by a BNB frustrated Lewis pair

2021 ◽  
Author(s):  
Xiongfei Zheng ◽  
Ili Zulkifly ◽  
Andreas Heilmann ◽  
Caitilín McManus ◽  
Simon Aldridge
Keyword(s):  
Carbon Monoxide ◽  
Metal Free ◽  
Frustrated Lewis Pair
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