ChemInform Abstract: Palladium-Catalyzed Three-Component Coupling Reactions of 2-(Cyanomethyl)phenol, Aryl Halides, and Carbon Monoxide.

ChemInform ◽  
2015 ◽  
Vol 46 (42) ◽  
pp. no-no
Author(s):  
Masahito Murai ◽  
Kazuhiro Okamoto ◽  
Koji Miki ◽  
Kouichi Ohe
Keyword(s):  
Carbon Monoxide ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Palladium Catalyzed ◽  
Three Component Coupling

Palladium-catalyzed three-component coupling reactions of 2-(cyanomethyl)phenol, aryl halides, and carbon monoxide

Tetrahedron ◽  
2015 ◽  
Vol 71 (26-27) ◽  
pp. 4432-4437 ◽  
Author(s):  
Masahito Murai ◽  
Kazuhiro Okamoto ◽  
Koji Miki ◽  
Kouichi Ohe
Keyword(s):  
Carbon Monoxide ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Palladium Catalyzed ◽  
Three Component Coupling

ChemInform Abstract: A General and Efficient Catalyst for Palladium-Catalyzed C-O Coupling Reactions of Aryl Halides with Primary Alcohols.

ChemInform ◽  
2010 ◽  
Vol 42 (4) ◽  
pp. no-no
Author(s):  
Saravanan Gowrisankar ◽  
Alexey G. Sergeev ◽  
Pazhamalai Anbarasan ◽  
Anke Spannenberg ◽  
Helfried Neumann ◽  
...  
Keyword(s):  
Aryl Halides ◽  
Coupling Reactions ◽  
Primary Alcohols ◽  
Efficient Catalyst ◽  
Palladium Catalyzed

Stereodivergent Hydrosilylation, Hydrostannylation, and Hydrogermylation of α-Trifluoromethylated Alkynes and Their Synthetic Applications

Synthesis ◽  
2016 ◽  
Vol 48 (19) ◽  
pp. 3317-3330 ◽  
Author(s):  
Cédric Tresse ◽  
Stéphane Schweizer ◽  
Philippe Bisseret ◽  
Jacques Lalevée ◽  
Gwilherm Evano ◽  
...  
Keyword(s):  
Functional Group ◽  
Cross Coupling ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Palladium Catalyzed

Stereoselective hydrometalation reactions of aryl- and alkyl-substituted trifluoromethylated alkynes with triethylsilane, tributylstannane, and triphenylgermane have been investigated. (E)-α-CF3-Vinylsilanes, -stannanes, and -germanes were obtained under palladium-catalyzed conditions whereas the corresponding (Z)-α-CF3-vinylgermanes were obtained under radical conditions. These reactions proceed in good to excellent yields and possess a broad functional group tolerance. Applications of the (Z)- and (E)-α-CF3-vinylgermanes in palladium-catalyzed cross-coupling reactions with aryl halides having diverse electronic requirements were also investigated. The corresponding (Z)- and (E)-α-CF3-styrenes were obtained as single isomers, thus demonstrating the utility of these versatile synthons for the synthesis of stereodefined trifluoromethylated alkenes.

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