scholarly journals Bimodal Evans–Polanyi Relationships in Hydrogen Atom Transfer from C(sp3)–H Bonds to the Cumyloxyl Radical. A Combined Time-Resolved Kinetic and Computational Study

2021 ◽  
Author(s):  
Michela Salamone ◽  
Marco Galeotti ◽  
Eduardo Romero-Montalvo ◽  
Jeffrey A. van Santen ◽  
Benjamin D. Groff ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Computational Study ◽  
Hydrogen Atom Transfer ◽  
Atom Transfer ◽  
Time Resolved

Carbon-to-Metal Hydrogen Atom Transfer:  Direct Observation Using Time-Resolved Infrared Spectroscopy

2005 ◽  
Vol 127 (45) ◽  
pp. 15684-15685 ◽  
Author(s):  
Jie Zhang ◽  
David C. Grills ◽  
Kuo-Wei Huang ◽  
Etsuko Fujita ◽  
R. Morris Bullock
Keyword(s):  
Infrared Spectroscopy ◽  
Hydrogen Atom ◽  
Direct Observation ◽  
Hydrogen Atom Transfer ◽  
Atom Transfer ◽  
Time Resolved ◽  
Time Resolved Infrared Spectroscopy

Iron-catalyzed hydrogen atom transfer induced cyclization of 1,6-enynes for the synthesis of ketoximes: a combined experimental and computational study

2021 ◽  
Author(s):  
Mingming Zhao ◽  
Wei He ◽  
Liang-Hua Zou ◽  
Dawei Wang ◽  
Tian-Yu Sun ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Computational Study ◽  
Hydrogen Atom Transfer ◽  
Radical Cyclization ◽  
Atom Transfer

An iron-catalyzed reductive radical cyclization/hydro-oximation of 1,6-enynes with tBuONO was developed, leading to functionalized benzofuran, benzothiophene, and cyclopentenyl-based ketoximes.

Analysis of Hydrogen Atom Transfer in Photoexcited Indole(NH3)nClusters by Femtosecond Time-Resolved Photoelectron Spectroscopy†

2003 ◽  
Vol 107 (40) ◽  
pp. 8239-8250 ◽  
Author(s):  
H. Lippert ◽  
V. Stert ◽  
L. Hesse ◽  
C. P. Schulz ◽  
I. V. Hertel ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Photoelectron Spectroscopy ◽  
Hydrogen Atom Transfer ◽  
Atom Transfer ◽  
Time Resolved

Time-resolved CIDNP effects in the reaction of hydrogen atom transfer in photolysis of benzaldehyde in solution

1988 ◽  
Vol 24 (3) ◽  
pp. 314-319
Author(s):  
Yu. P. Tsentalovich ◽  
A. A. Obynochnyi ◽  
M. V. Burlov ◽  
R. Z. Sagdeev ◽  
P. Burkhard
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Atom Transfer ◽  
Atom Transfer ◽  
Time Resolved

Mechanistic insights into Ni-catalyzed hydrogen atom transfer (HAT)-triggered hydrodefluorination of CF3‑Substituted Alkenes

2021 ◽  
Author(s):  
Jiandong Guo ◽  
Dongju Zhang ◽  
Xiaotai Wang
Keyword(s):  
Hydrogen Atom ◽  
Catalytic Reaction ◽  
Computational Study ◽  
Hydrogen Atom Transfer ◽  
Atom Transfer ◽  
Nickel Hydride

We report the first computational study on a nickel hydride HAT-initiated catalytic reaction, a novel hydrodefluorination of CF3-substituted aryl alkenes to afford gem-difluoroalkenes. The study gains detailed mechanistic insights into...

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