Substituent Effects on the Reactivity of the Silicon−Carbon Double Bond. Resonance, Inductive, and Steric Effects of Substituents at Silicon on the Reactivity of Simple 1-Methylsilenes

William J. Leigh; Rabah Boukherroub; Corinna Kerst

doi:10.1021/ja981435d

Substituent Effects on the Reactivity of the Silicon−Carbon Double Bond. Resonance, Inductive, and Steric Effects of Substituents at Silicon on the Reactivity of Simple 1-Methylsilenes

Journal of the American Chemical Society ◽

10.1021/ja981435d ◽

1998 ◽

Vol 120 (37) ◽

pp. 9504-9512 ◽

Cited By ~ 25

Author(s):

William J. Leigh ◽

Rabah Boukherroub ◽

Corinna Kerst

Keyword(s):

Double Bond ◽

Substituent Effects ◽

Steric Effects ◽

Carbon Double Bond ◽

Silicon Carbon

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ChemInform Abstract: Substituent Effects on the Reactivity of the Silicon-Carbon Double Bond. Resonance, Inductive, and Steric Effects of Substituents at Silicon on the Reactivity of Simple 1-Methylsilenes.

ChemInform ◽

10.1002/chin.199903164 ◽

2010 ◽

Vol 30 (3) ◽

pp. no-no

Author(s):

W. J. LEIGH ◽

R. BOUKHERROUB ◽

C. KERST

Keyword(s):

Double Bond ◽

Substituent Effects ◽

Steric Effects ◽

Carbon Double Bond ◽

Silicon Carbon

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Substituent Effects on the Reactivity of the Silicon−Carbon Double Bond. Mechanistic Studies of the Ene-Addition of Acetone to Reactive Arylsilenes

Organometallics ◽

10.1021/om970875v ◽

1998 ◽

Vol 17 (4) ◽

pp. 645-651 ◽

Cited By ~ 11

Author(s):

Christine J. Bradaric ◽

William J. Leigh

Keyword(s):

Double Bond ◽

Substituent Effects ◽

Mechanistic Studies ◽

Carbon Double Bond ◽

Silicon Carbon ◽

Ene Addition

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Substituent Effects on the Reactivity of the Silicon−Carbon Double Bond

Accounts of Chemical Research ◽

10.1021/ar960252y ◽

2001 ◽

Vol 34 (2) ◽

pp. 129-136 ◽

Cited By ~ 65

Author(s):

Tracy L. Morkin ◽

William J. Leigh

Keyword(s):

Double Bond ◽

Substituent Effects ◽

Carbon Double Bond ◽

Silicon Carbon

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ChemInform Abstract: Substituent Effects on the Reactivity of the Silicon-Carbon Double Bond

ChemInform ◽

10.1002/chin.200118254 ◽

2001 ◽

Vol 32 (18) ◽

pp. no-no

Author(s):

Tracy L. Morkin ◽

William J. Leigh

Keyword(s):

Double Bond ◽

Substituent Effects ◽

Carbon Double Bond ◽

Silicon Carbon

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Substituent Effects on the Reactivity of the Silicon−Carbon Double Bond. Substituted 1,1-Dimethylsilenes from Far-UV Laser Flash Photolysis of α-Silylketenes and (Trimethylsilyl)diazomethane

Journal of the American Chemical Society ◽

10.1021/ja984277z ◽

1999 ◽

Vol 121 (20) ◽

pp. 4744-4753 ◽

Cited By ~ 17

Author(s):

William J. Leigh ◽

Corinna Kerst ◽

Rabah Boukherroub ◽

Tracy L. Morkin ◽

Stephen I. Jenkins ◽

...

Keyword(s):

Double Bond ◽

Flash Photolysis ◽

Laser Flash Photolysis ◽

Substituent Effects ◽

Laser Flash ◽

Uv Laser ◽

Carbon Double Bond ◽

Silicon Carbon ◽

Trimethylsilyl Diazomethane

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Intramolecular rearrangements of silenes II . Synthesis of 1-methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl-1-silacyclobutane via [4 → 2 + 2]thermocyclodecomposition — transient silene rearrangement sequence. Novel 1,4-hydrogen shift from aryl carbon to sp2 silicon of the silicon-carbon double bond

Journal of Organometallic Chemistry ◽

10.1016/0022-328x(95)05415-l ◽

1995 ◽

Vol 492 (1) ◽

pp. C4-C7 ◽

Cited By ~ 5

Author(s):

Leonid E Gusel'nikov ◽

Vera V Volkova ◽

Boris D Lavrukhin

Keyword(s):

Double Bond ◽

Hydrogen Shift ◽

Intramolecular Rearrangements ◽

Carbon Double Bond ◽

Silicon Carbon

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The silicon-carbon double bond: a healthy rivalry between theory and experiment

Accounts of Chemical Research ◽

10.1021/ar00081a003 ◽

1982 ◽

Vol 15 (9) ◽

pp. 283-290 ◽

Cited By ~ 105

Author(s):

Henry F. Schaefer

Keyword(s):

Double Bond ◽

Carbon Double Bond ◽

Silicon Carbon ◽

Theory And Experiment

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How strong is the silicon carbon double bond in fluoro- and methyl-substituted silaethylenes? An experimental determination of .pi. bond strengths

Journal of the American Chemical Society ◽

10.1021/ja00161a002 ◽

1990 ◽

Vol 112 (5) ◽

pp. 1672-1677 ◽

Cited By ~ 12

Author(s):

C. E. Allison ◽

T. B. McMahon

Keyword(s):

Double Bond ◽

Experimental Determination ◽

Carbon Double Bond ◽

Silicon Carbon ◽

Bond Strengths

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Formation of an unstable silicon-carbon double bond in the photodecomposition of trimethylsilyldiazoacetate

Journal of the American Chemical Society ◽

10.1021/ja00803a058 ◽

1973 ◽

Vol 95 (22) ◽

pp. 7518-7519 ◽

Cited By ~ 22

Author(s):

Wataru. Ando ◽

Tsuneo. Hagiwara ◽

Toshihiko. Migita

Keyword(s):

Double Bond ◽

Carbon Double Bond ◽

Silicon Carbon

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ChemInform Abstract: CHEMISTRY OF SILYLCARBENE. V. 1,2-SILAOXETANE INTERMEDIATE IN THE GAS PHASE DECOMPOSITION OF SILYL PHENYL KETONES. NEW ROUTE FOR THE FORMATION OF A SILICON-CARBON DOUBLE BOND

Chemischer Informationsdienst ◽

10.1002/chin.197607257 ◽

1976 ◽

Vol 7 (7) ◽

pp. no-no

Author(s):

WATARU ANDO ◽

AKIRA SEKIGUCHI ◽

TOSHIHIKO MIGITA

Keyword(s):

Double Bond ◽

Gas Phase ◽

Phase Decomposition ◽

Carbon Double Bond ◽

Silicon Carbon ◽

Phenyl Ketones

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