How strong is the silicon carbon double bond in fluoro- and methyl-substituted silaethylenes? An experimental determination of .pi. bond strengths

C. E. Allison; T. B. McMahon

doi:10.1021/ja00161a002

How strong is the silicon carbon double bond in fluoro- and methyl-substituted silaethylenes? An experimental determination of .pi. bond strengths

Journal of the American Chemical Society ◽

10.1021/ja00161a002 ◽

1990 ◽

Vol 112 (5) ◽

pp. 1672-1677 ◽

Cited By ~ 12

Author(s):

C. E. Allison ◽

T. B. McMahon

Keyword(s):

Double Bond ◽

Experimental Determination ◽

Carbon Double Bond ◽

Silicon Carbon ◽

Bond Strengths

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Substituent Effects on the Reactivity of the Silicon−Carbon Double Bond. Mechanistic Studies of the Ene-Addition of Acetone to Reactive Arylsilenes

Organometallics ◽

10.1021/om970875v ◽

1998 ◽

Vol 17 (4) ◽

pp. 645-651 ◽

Cited By ~ 11

Author(s):

Christine J. Bradaric ◽

William J. Leigh

Keyword(s):

Double Bond ◽

Substituent Effects ◽

Mechanistic Studies ◽

Carbon Double Bond ◽

Silicon Carbon ◽

Ene Addition

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Intramolecular rearrangements of silenes II . Synthesis of 1-methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl-1-silacyclobutane via [4 → 2 + 2]thermocyclodecomposition — transient silene rearrangement sequence. Novel 1,4-hydrogen shift from aryl carbon to sp2 silicon of the silicon-carbon double bond

Journal of Organometallic Chemistry ◽

10.1016/0022-328x(95)05415-l ◽

1995 ◽

Vol 492 (1) ◽

pp. C4-C7 ◽

Cited By ~ 5

Author(s):

Leonid E Gusel'nikov ◽

Vera V Volkova ◽

Boris D Lavrukhin

Keyword(s):

Double Bond ◽

Hydrogen Shift ◽

Intramolecular Rearrangements ◽

Carbon Double Bond ◽

Silicon Carbon

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The silicon-carbon double bond: a healthy rivalry between theory and experiment

Accounts of Chemical Research ◽

10.1021/ar00081a003 ◽

1982 ◽

Vol 15 (9) ◽

pp. 283-290 ◽

Cited By ~ 105

Author(s):

Henry F. Schaefer

Keyword(s):

Double Bond ◽

Carbon Double Bond ◽

Silicon Carbon ◽

Theory And Experiment

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ChemInform Abstract: How Strong is the Si=C Bond in Fluoro- and Methyl-Substituted Silaethylenes? An Experimental Determination of π Bond Strengths.

ChemInform ◽

10.1002/chin.199023071 ◽

1990 ◽

Vol 21 (23) ◽

Author(s):

C. E. ALLISON ◽

T. B. MCMAHON

Keyword(s):

Experimental Determination ◽

Bond Strengths

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Formation of an unstable silicon-carbon double bond in the photodecomposition of trimethylsilyldiazoacetate

Journal of the American Chemical Society ◽

10.1021/ja00803a058 ◽

1973 ◽

Vol 95 (22) ◽

pp. 7518-7519 ◽

Cited By ~ 22

Author(s):

Wataru. Ando ◽

Tsuneo. Hagiwara ◽

Toshihiko. Migita

Keyword(s):

Double Bond ◽

Carbon Double Bond ◽

Silicon Carbon

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ChemInform Abstract: CHEMISTRY OF SILYLCARBENE. V. 1,2-SILAOXETANE INTERMEDIATE IN THE GAS PHASE DECOMPOSITION OF SILYL PHENYL KETONES. NEW ROUTE FOR THE FORMATION OF A SILICON-CARBON DOUBLE BOND

Chemischer Informationsdienst ◽

10.1002/chin.197607257 ◽

1976 ◽

Vol 7 (7) ◽

pp. no-no

Author(s):

WATARU ANDO ◽

AKIRA SEKIGUCHI ◽

TOSHIHIKO MIGITA

Keyword(s):

Double Bond ◽

Gas Phase ◽

Phase Decomposition ◽

Carbon Double Bond ◽

Silicon Carbon ◽

Phenyl Ketones

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A theoretical study of the silicon—carbon double bond

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(00)91487-6 ◽

1974 ◽

Vol 66 (2) ◽

pp. 241-247 ◽

Cited By ~ 22

Author(s):

R. Damrauer ◽

D.R. Williams

Keyword(s):

Double Bond ◽

Theoretical Study ◽

Carbon Double Bond ◽

Silicon Carbon

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ChemInform Abstract: THE SYNTHESIS AND PYROLYTIC REARRANGEMENT OF PHTHALATE ESTERS OF SOME TERTIARY SILANOLS, AN ATTEMPT TO PREPARE A SILICON CARBON DOUBLE BOND SPECIES

Chemischer Informationsdienst ◽

10.1002/chin.197517331 ◽

1975 ◽

Vol 6 (17) ◽

pp. no-no

Author(s):

K. G. RUTHERFORD ◽

R. J. SEIDEWAND

Keyword(s):

Double Bond ◽

Phthalate Esters ◽

Carbon Double Bond ◽

Silicon Carbon

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The First Spectroscopic Observation of an Equilibrium between a Digermene and Germylenes and Experimental Determination of a Bond Dissociation Energy of a Ge-Ge Double Bond

Chemistry Letters ◽

10.1246/cl.1998.239 ◽

1998 ◽

Vol 27 (3) ◽

pp. 239-240 ◽

Cited By ~ 29

Author(s):

Kuniyuki Kishikawa ◽

Norihiro Tokitoh ◽

Renji Okazaki

Keyword(s):

Double Bond ◽

Experimental Determination ◽

Bond Dissociation Energy ◽

Dissociation Energy ◽

Spectroscopic Observation ◽

Bond Dissociation

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On the experimental–theoretical discrepancy regarding the silicon–carbon double bond length

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39840000768 ◽

1984 ◽

pp. 768-768 ◽

Cited By ~ 3

Author(s):

Yitzhak Apeloig ◽

Miriam Karni

Keyword(s):

Double Bond ◽

Bond Length ◽

Carbon Double Bond ◽

Silicon Carbon

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