Asymmetric Aldol Additions with Titanium Enolates of Acyloxazolidinethiones:  Dependence of Selectivity on Amine Base and Lewis Acid Stoichiometry

Michael T. Crimmins; Bryan W. King; Elie A. Tabet

doi:10.1021/ja9716721

Asymmetric Aldol Additions with Titanium Enolates of Acyloxazolidinethiones: Dependence of Selectivity on Amine Base and Lewis Acid Stoichiometry

Journal of the American Chemical Society ◽

10.1021/ja9716721 ◽

1997 ◽

Vol 119 (33) ◽

pp. 7883-7884 ◽

Cited By ~ 160

Author(s):

Michael T. Crimmins ◽

Bryan W. King ◽

Elie A. Tabet

Keyword(s):

Lewis Acid ◽

Asymmetric Aldol ◽

Aldol Additions ◽

Titanium Enolates

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Titanium Enolates of Thiazolidinethione Chiral Auxiliaries: Versatile Tools for Asymmetric Aldol Additions

Organic Letters ◽

10.1021/ol9913901 ◽

2000 ◽

Vol 2 (6) ◽

pp. 775-777 ◽

Cited By ~ 148

Author(s):

Michael T. Crimmins ◽

Kleem Chaudhary

Keyword(s):

Chiral Auxiliaries ◽

Asymmetric Aldol ◽

Aldol Additions ◽

Titanium Enolates

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ChemInform Abstract: Titanium Enolates of Thiazolidinethione Chiral Auxiliaries: Versatile Tools for Asymmetric Aldol Additions.

ChemInform ◽

10.1002/chin.200027135 ◽

2010 ◽

Vol 31 (27) ◽

pp. no-no

Author(s):

Michael T. Crimmins ◽

Kleem Chaudhary

Keyword(s):

Chiral Auxiliaries ◽

Asymmetric Aldol ◽

Aldol Additions ◽

Titanium Enolates

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ChemInform Abstract: Asymmetric Total Synthesis of Callystatin A: Asymmetric Aldol Additions with Titanium Enolates of Acyloxazolidinethiones.

ChemInform ◽

10.1002/chin.199903226 ◽

2010 ◽

Vol 30 (3) ◽

pp. no-no

Author(s):

M. T. CRIMMINS ◽

B. W. KING

Keyword(s):

Total Synthesis ◽

Asymmetric Total Synthesis ◽

Asymmetric Aldol ◽

Aldol Additions ◽

Callystatin A ◽

Titanium Enolates

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Asymmetric Total Synthesis of Callystatin A: Asymmetric Aldol Additions with Titanium Enolates of Acyloxazolidinethiones

Journal of the American Chemical Society ◽

10.1021/ja9817500 ◽

1998 ◽

Vol 120 (35) ◽

pp. 9084-9085 ◽

Cited By ~ 87

Author(s):

Michael T. Crimmins ◽

Bryan W. King

Keyword(s):

Total Synthesis ◽

Asymmetric Total Synthesis ◽

Asymmetric Aldol ◽

Aldol Additions ◽

Callystatin A ◽

Titanium Enolates

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Dual Proline/Water Compatible Lewis Acid Activation: a Biomimetic Approach for Direct Asymmetric Aldol Reaction

10.3390/ecsoc-13-00193 ◽

2009 ◽

Author(s):

Maël Penhoat ◽

Christian Rolando ◽

Didier Barbry

Keyword(s):

Lewis Acid ◽

Aldol Reaction ◽

Acid Activation ◽

Asymmetric Aldol ◽

Asymmetric Aldol Reaction ◽

Biomimetic Approach

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Chiral Lewis Acid Controlled Synthesis (CLAC Synthesis): Chiral Lewis Acids Influence the Reaction Course in Asymmetric Aldol Reactions for the Synthesis of Enantiomeric Dihydroxythioester Derivatives in the Presence of Chiral Diamines Derived from L-Proline

Chemistry - A European Journal ◽

10.1002/chem.19970030914 ◽

1997 ◽

Vol 3 (9) ◽

pp. 1472-1481 ◽

Cited By ~ 27

Author(s):

Shū Kobayashi ◽

Mineko Horibe

Keyword(s):

Lewis Acid ◽

Lewis Acids ◽

Aldol Reactions ◽

Controlled Synthesis ◽

Asymmetric Aldol ◽

Chiral Lewis Acid ◽

Chiral Diamines

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ChemInform Abstract: Lewis Acid Promoted Aldol Additions of α-Thiosilylketene Acetals to a-Alkoxy Aldehydes: Diastereoselective Synthesis of syn-α-Methylene-β-hydroxy-γ-alkoxy Esters.

Chemischer Informationsdienst ◽

10.1002/chin.198617191 ◽

1986 ◽

Vol 17 (17) ◽

Author(s):

A. BERNARDI ◽

S. CARDANI ◽

C. GENNARI ◽

G. POLI ◽

C. SCOLASTICO

Keyword(s):

Lewis Acid ◽

Diastereoselective Synthesis ◽

Aldol Additions

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Catalytic asymmetric aldol reactions. Use of a chiral (acyloxy)borane complex as a versatile Lewis-acid catalyst

Journal of the American Chemical Society ◽

10.1021/ja00003a047 ◽

1991 ◽

Vol 113 (3) ◽

pp. 1041-1042 ◽

Cited By ~ 135

Author(s):

Kyoji Furuta ◽

Tohru Maruyama ◽

Hisashi Yamamoto

Keyword(s):

Lewis Acid ◽

Acid Catalyst ◽

Aldol Reactions ◽

Asymmetric Aldol ◽

Lewis Acid Catalyst ◽

Catalytic Asymmetric

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ChemInform Abstract: The Chemistry of Trichlorosilyl Enolates. Part 2. Highly-Selective Asymmetric Aldol Additions of Ketone Enolates.

ChemInform ◽

10.1002/chin.199724042 ◽

2010 ◽

Vol 28 (24) ◽

pp. no-no

Author(s):

S. E. DENMARK ◽

K.-T. WONG ◽

R. A. STAVENGER

Keyword(s):

Asymmetric Aldol ◽

Aldol Additions ◽

Ketone Enolates

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ChemInform Abstract: Catalytic Asymmetric Aldol Reactions. Use of a Chiral (Acyloxy)borane Complex as a Versatile Lewis Acid Catalyst.

ChemInform ◽

10.1002/chin.199121074 ◽

2010 ◽

Vol 22 (21) ◽

pp. no-no

Author(s):

K. FURUTA ◽

T. MARUYAMA ◽

H. YAMAMOTO

Keyword(s):

Lewis Acid ◽

Acid Catalyst ◽

Aldol Reactions ◽

Asymmetric Aldol ◽

Lewis Acid Catalyst ◽

Catalytic Asymmetric

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